Home Categories Organic Chemistry tert-Butyl nitrite
A1235512

tert-Butyl nitrite , 90% , 540-80-7

CAS NO.:540-80-7

Empirical Formula: C4H9NO2

Molecular Weight: 103.12

MDL number: MFCD00002055

EINECS: 208-757-0

Pack Size Price Stock Quantity
25ML RMB38.40 In Stock
100ML RMB104.00 In Stock
250ML RMB199.20 In Stock
500ML RMB375.20 In Stock
2.5L RMB1489.60 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 61-63 °C(lit.)
Density  0.867 g/mL at 25 °C(lit.)
vapor pressure  13.466kPa at 25℃
refractive index  n20/D 1.368(lit.)
Flash point: −10 °F
storage temp.  2-8°C
solubility  alcohol: very soluble(lit.)
form  Liquid
color  Clear yellow
Water Solubility  slightly soluble
Merck  14,1583
BRN  1209339
LogP 2.24 at 20℃
CAS DataBase Reference 540-80-7(CAS DataBase Reference)
NIST Chemistry Reference (CH3)3CONO(540-80-7)

Description and Uses

tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.

Safety

Symbol(GHS) 
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302+H332
Precautionary statements  P210-P233-P240-P241-P301+P312-P304+P340+P312
Hazard Codes  F,Xn
Risk Statements  11-20/22
Safety Statements  16-24-46
RIDADR  UN 2351 3/PG 2
WGK Germany  1
RTECS  RA0802000
8
HazardClass  3
PackingGroup  II
HS Code  29209085

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