Gamma-BHC solution , analyticalstandard,100ug/mlinpetroleumether , 58-89-9
Synonym(s):
Lindane;γ-BHC;gamma-hexachlorocyclohexane;1α,2α,3β,4α,5α,6β-Hexachlorocyclohexane;γ-1,2,3,4,5,6-Hexachlorocyclohexane
CAS NO.：58-89-9
Empirical Formula: C6H6Cl6
Molecular Weight: 290.81
MDL number: MFCD00135947
EINECS: 200-401-2
PRODUCT Properties
| Melting point: | 113-115 °C(lit.) |
| Boiling point: | 373.64°C (rough estimate) |
| Density | 1.7152 (rough estimate) |
| vapor pressure | 28.0, 55.3, 87.0, 168.8, 285.8, 297.0, and 538.5 at 19.58, 24.95, 28.42, 33.58, 37.82, 37.86, and43.32 °C, respectively (Boehncke et al., 1996) |
| refractive index | nD20 1.644 |
| Flash point: | 11 °C |
| storage temp. | 0-6°C |
| solubility | H2O: insoluble0.01g/L (practically) |
| Water Solubility | 7.3 mg l-1 (25 °C) |
| Merck | 13,5523 |
| BRN | 1907337 |
| Henry's Law Constant | 12.8 at 5 °C, 14.8 at 15 °C, 18.8 at 20 °C, 26.6 at 25 °C, 38.5 at 35 °C (gas stripping-GC, Cetin et
al., 2006) |
| Exposure limits | NIOSH REL: TWA 0.5 mg/m3, IDLH 50 mg/m3; OSHA PEL: TWA
0.5 mg/m3; ACGIH TLV: TWA 0.5 mg/m3. |
| Stability: | Stable. Incompatible with strong oxidizing agents. |
Description and Uses
Lindane is one of eight different hexachlorocyclohexane (HCH), [58-89-9], C6H6Cl6, isomers and its Chemical Abstract name is 1α, 2α,3β,4α,5α,6β- hexachlorocyclohexane 58-89-9 (γ-HCH or γ -BHC, benzene hexachloride) (80). Commercial products containing lindane are marketed as either a mixture of isomers or as the pure γ -BHC isomer. Not unexpectedly, lindane is a highly stable lipophilic compound and it has been used extensively worldwide as an insecticide. In contrast, hexachloropentadiene, [77-47-4], C5Cl6, is an extremely reactive industrial intermediate used as a chemical intermediate in the synthesis of a broad range of cyclodiene-derived pesticides, which include endosulfan, endrin, heptachlor, and several different organohalogen flame retardants (81).
The only identified uses for hexachlorocyclohexane-containing products are based on the insecticidal activity of the γ isomer (lindane), which is considered to be the only insecticidally effective component (Extoxnet 1996). Lindane or technical-grade hexachlorocyclohexane containing the γ isomer is used primarily as an insecticide in the treatment of wood and wooden structures, seed grains, and livestock (ATSDR 2005, HSDB 2009). Other major uses are as an insecticide for several dozen fruit and vegetable crops, in baits and seed treatments for rodent control, and for treatment of scabies (mites) and lice. It is approved by the U.S. Food and Drug Administration foruse in three products for the treatment of lice and scabies (one lotionand two shampoos) (FDA 2009). Agricultural and pesticide uses accounted for about 270,000 kg (594,000 lb) of lindane and 450,000 kg (1 million pounds) of technical-grade hexachlorocyclohexane in 1974;the remaining uses were industrial or pharmaceutical (IARC 1979).
Safety
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H301-H312+H332-H362-H373-H410 |
| Precautionary statements | P260-P263-P273-P280-P301+P310-P302+P352+P312 |
| Hazard Codes | T,N,F,Xn,Xi |
| Risk Statements | 20/21-25-48/22-50/53-64-39/23/24/25-23/24/25-11-67-65-38-52/53-62-48/20-40-21 |
| Safety Statements | 36/37-45-60-61-62-33-29-16-9-7-22 |
| OEB | C |
| OEL | TWA: 0.5 mg/m3 [skin] |
| RIDADR | UN 2811 6.1/PG 1 |
| WGK Germany | 3 |
| RTECS | GV4900000 |
| HazardClass | 6.1(b) |
| PackingGroup | III |
| HS Code | 2903810000 |
| Toxicity | LD50 in male, female rats (mg/kg): 88, 91 orally (Gaines) |
| IDLA | 50 mg/m3 |