Home Categories Inorganic chemistry Magnesium perchlorate
A0633012

Magnesium perchlorate , ACS, dry level, for water absorption , 10034-81-8

CAS NO.:10034-81-8

Empirical Formula: 2ClO4.Mg

Molecular Weight: 223.2

MDL number: MFCD00274167

EINECS: 233-108-3

Update time: 2022-07-08

PRODUCT Properties

Melting point: 251 °C
Density  2,21 g/cm3
vapor pressure  0Pa at 25℃
storage temp.  Hygroscopic, Room Temperature, Under inert atmosphere
solubility  Ethanol (Slightly), Water (Slightly)
form  Solid
Specific Gravity 2.21
color  White
Water Solubility  Magnesium perchlorate is soluble in water, ethanol.
Sensitive  Hygroscopic
Merck  14,5678
Stability: Stable, but moisture sensitive. Oxidizer - contact with combustible material may lead to fire. Incompatible with reducing agents, organic materials, trimethyl phosphate, powdered metals, strong acids, phosphorus.
LogP -6.53 at 25℃
CAS DataBase Reference 10034-81-8(CAS DataBase Reference)
EPA Substance Registry System Perchloric acid, magnesium salt (2:1) (10034-81-8)

Description and Uses

Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO4)2. Magnesium perchlorate decomposes at 250°C. The heat of formation is 568.90 kJ/mol. If water is added to magnesium perchlorate, the reaction is highly exothermic and may cause damage to the eyes. Thus, this salt should be added to a sufficient amount of water in order to form a dilute solution.
Mg(ClO4)2·6H2O is composed of white, deliquescent crystals which are soluble in water and alcohol but explosive when in contact with reducing materials. This compound is used as a drying agent for gases. This salt is highly exothermic when added to water and releases steamy HCl gas. It can be dried to form the anhydrate by heating to 250°C under vacuum. The hexahydrate losses two molecules of water at 244°C in air and further decomposes to the dihydrate at 336°C and the anhydrate at 438°C.
The anhydrate has been used as a desiccant to dry gas streams or air samples. However, it is no longer used since perchlorates tend to form explosive compounds with a variety of organic materials as well as other substances.

Magnesium perchlorate is commonly utilized as a potent oxidizing agent. It is used as dehydrating agent in organic synthesis. It is practiced in many domains like pharma industry, pyrotechnics industry,in rechargeable batteries and it is a versatile tool in organic synthesis. It possesses photoelectronic and optical properties. Thus it can be used in photo electronic and optoelectronic devices. It is applied as a strong drying agent for gases.

Safety

Symbol(GHS) 
GHS03,GHS07
Signal word  Danger
Hazard statements  H272-H315-H319-H335
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  O,Xi
Risk Statements  8-36/37/38-14/15
Safety Statements  17-26-27-36/37/39-43-7/8
RIDADR  UN 1475 5.1/PG 2
WGK Germany  3
RTECS  SC8925000
3-10
TSCA  Yes
HazardClass  5.1
PackingGroup  II
HS Code  28299010
Hazardous Substances Data 10034-81-8(Hazardous Substances Data)
Toxicity LD50 ipr-mus: 1500 mg/kg JAFCAU 14,512,66

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