T9132730
Bis(trimethylsilyl) Sulfide , >97.0%(GC) , 3385-94-2
Synonym(s):
(TMS)2S;Bis(trimethylsilyl) sulfide;HMDS;NSC 252160
CAS NO.：3385-94-2
Empirical Formula: C6H18SSi2
Molecular Weight: 178.44
MDL number: MFCD00014851
EINECS: 222-201-4
| Pack Size | Price | Stock | Quantity |
| 5g | RMB1016.00 | In Stock |
|
| 25g | RMB3992.00 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Boiling point: | 164 °C(lit.) |
| Density | 0.846 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 79 °F |
| storage temp. | Flammables area |
| solubility | Miscible with terahydrofuran and toluene. |
| form | Liquid |
| color | Colorless |
| Specific Gravity | 0.851 |
| Water Solubility | Soluble in tetrahydrofuran and toluene. Hydrolyzes in water. |
| Sensitive | Air Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 1740046 |
| Stability: | store cold |
Description and Uses
Hexamethyldisilathiane may be used in the bis-O-demethylation of dimethoxy aromatic compounds.
It may also be used as a sulfur source in the following conversion:
- Amides and lactams to their corresponding sulfur analogs.
- Allyl alcohols to diallyl sulfides.
- Transition metal halides to metal sulfides.
- Aryl iodides to diaryl sulfides.
Safety
| Symbol(GHS) |   GHS02,GHS06 |
| Signal word | Danger |
| Hazard statements | H226-H301+H311+H331 |
| Precautionary statements | P210-P280-P301+P310+P330-P302+P352+P312-P304+P340+P311 |
| Hazard Codes | T |
| Risk Statements | 10-23/24/25 |
| Safety Statements | 36/37/39-45 |
| RIDADR | UN 1993 3/PG 3 |
| WGK Germany | 3 |
| F | 10-13-21 |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | II |
| HS Code | 29319090 |
