PRODUCT Properties
Melting point: | -11 °C |
Boiling point: | 106 °C(lit.) |
Density | 0.930 g/mL at 20 °C |
vapor density | 3 (vs air) |
vapor pressure | 23 mm Hg ( 20 °C) |
refractive index | n |
FEMA | 2908 | PIPERIDINE |
Flash point: | 16 °C(lit.) |
storage temp. | Store in dark! |
solubility | miscible in water and alcohol; soluble in ether, acetone, benzene and
chloroform
maximum allowable concentration: not established; more toxic, irritating and
volatile than pyridine (Reinhardt and Brittelli 1981). |
pka | 11.123(at 25℃) |
PH | 12.6 (100g/l, H2O, 20°C) |
Odor | at 1.00 % in propylene glycol. heavy sweet floral animal |
Odor Type | animal |
explosive limit | 1.5-10.3%(V) |
Water Solubility | Miscible |
Sensitive | Air Sensitive |
Merck | 14,7468 |
JECFA Number | 1607 |
BRN | 102438 |
Dielectric constant | 5.9(20℃) |
Stability: | Stable. Highly flammable. Incompatible with strong oxidizing agents, strong acids, organic acids, water. Vapours may flow along surfaces to a distant source of ignition. |
LogP | 0.61 |
CAS DataBase Reference | 110-89-4(CAS DataBase Reference) |
NIST Chemistry Reference | Piperidine(110-89-4) |
EPA Substance Registry System | Piperidine (110-89-4) |
Description and Uses
It is used in organic synthesis, especially inthe preparation of many crystalline derivativesof aromatic nitro compounds.
Safety
Symbol(GHS) | GHS02,GHS05,GHS06 |
Signal word | Danger |
Hazard statements | H225-H302-H311+H331-H314 |
Precautionary statements | P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
Hazard Codes | T,F |
Risk Statements | 61-10-20/21-34-23/24-11-52-24-20/22 |
Safety Statements | 53-16-26-36/37/39-45-27 |
RIDADR | UN 3286 3/PG 2 |
WGK Germany | 3 |
RTECS | TM3500000 |
F | 3-34 |
Autoignition Temperature | 320 °C |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | I |
HS Code | 29333210 |
Hazardous Substances Data | 110-89-4(Hazardous Substances Data) |
Toxicity | LD50 orally in rats: 0.52 ml/kg (Smyth) |