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S590779

powder,-60 mesh,99.7%tracemetalsbasis,Sr:<0.8% , 12047-79-9

Synonym(s):
Tribarium dinitride

CAS NO.:12047-79-9

Empirical Formula: Ba3N2

Molecular Weight: 439.99

MDL number: MFCD00049718

EINECS: 234-977-1

Pack Size Price Stock Quantity
1g RMB812.30 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 1000, vacuum [ALF93]
Density  4.780
solubility  reacts with H2O
form  Powder
color  black
Water Solubility  decomposed in H2O [CRC10]
EPA Substance Registry System Barium nitride (Ba3N2) (12047-79-9)

Description and Uses

Barium nitride purportedly has the molecular formula of Ba3N2 and the molecular weight of 439.9944 g/mol. Its CAS number is 12047-79-9. It is offered for sale by several reputable manufacturers but the actual composition and identity may not coincide with the formula presented. Although Mg, Ca (and to some extent Sr) forms a number of compounds based upon the general formula M3N2, there is no report in the literature that or Ba forms such compositions. The literature is devoid of any data relating to Ba3N2 and the subnitride is mentioned only in the presence of Sr2N.
Barium nitride has been reported to be metastable and sublimes in the 915 to 1050 C temperature range. The reported equation for this behavior is: log P = 6.38 × 104/T(K) and it decomposes when heated beyond this range to form the metal and nitrogen gas, i.e. it is metastable. Thus, the existence of barium nitride is doubtful and no report of its formation or properties exists to date.

Barium nitride is a ceramic that finds use as a dopant in optical materials such as white emitting LEDs. Ba3N2 is also used as a synthetic precursor for ternary metal nitrides and as a flux growth medium for GaN.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302+H332
Precautionary statements  P261-P264-P270-P271-P301+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/22
Safety Statements  28
RIDADR  UN 2813 4.3 / PGI
WGK Germany  3
Toxicity LD50 orl-mus: 46,100 mg/kg TOIZAG 22,119,75

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