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S1749650

ReagentPlus ,≥99% , 120-61-6

Synonym(s):
Manganese dichloride monohydrate

CAS NO.:120-61-6

Empirical Formula: Cl2H2MnO

Molecular Weight: 143.86

MDL number: MFCD00149793

EINECS: 613-575-3

Pack Size Price Stock Quantity
500G RMB217.67 In Stock
3KG RMB873.97 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 122 °C(lit.)
Density  1.913 g/mL at 25 °C(lit.)
storage temp.  Hygroscopic, Room Temperature, under inert atmosphere
solubility  Methanol (Slightly), Water (Slightly)
form  Solid
color  Pale Pink to Light Red

Description and Uses

Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.

Safety

Symbol(GHS) 
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H318-H373-H411
Precautionary statements  P260-P273-P280-P301+P310-P305+P351+P338-P314
Hazard Codes  Xn
Risk Statements  22-36/37/38-52
Safety Statements  26-36/37-45-61-36-22
WGK Germany  1

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