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LN2174030

99.5% , 10112-91-1

Synonym(s):
Calomel;Mercurous chloride

CAS NO.:10112-91-1

Empirical Formula: Cl2Hg2

Molecular Weight: 472.09

MDL number: MFCD00011043

EINECS: 233-307-5

Update time: 2022-07-08

PRODUCT Properties

Melting point: 400 °C (subl.)(lit.)
Boiling point: 383°C
Density  7.15
vapor pressure  1.7 mm Hg at 236 °C
storage temp.  Poison room
solubility  insoluble in ethanol, ethyl ether
form  powder
Specific Gravity 7.15
color  White
Odor Odorless
Water Solubility  Soluble in (0.002g/L )water.
Sensitive  Moisture & Light Sensitive
Merck  14,5894
Solubility Product Constant (Ksp) pKsp: 17.88(25°C)
Dielectric constant 7.0(Ambient)
Exposure limits ACGIH: TWA 0.025 mg/m3 (Skin)
NIOSH: IDLH 10 mg/m3; TWA 0.05 mg/m3; Ceiling 0.1 mg/m3
InChIKey ZOMNIUBKTOKEHS-UHFFFAOYSA-L
CAS DataBase Reference 10112-91-1(CAS DataBase Reference)
NIST Chemistry Reference Mercurous chloride(10112-91-1)
EPA Substance Registry System Mercurous chloride (10112-91-1)

Description and Uses

Mercury(I) chloride, a colorless solid also known as the mineral calomel, is the compound with the formula Hg2Cl2, with the connectivity Cl-Hg-Hg-Cl. It reacts with chlorine to form mercuric chloride, which resists further oxidation. Hg2Cl2 is a linear molecule. Mercurous chloride forms through the reaction of elemental mercury and mercuric chloride.
Hg + HgCl2→Hg2Cl2

Calomel is used as a laboratory reagent, as a fungicide, and as a depolarizer in dry batteries.

Safety

Symbol(GHS) 
GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302+H312-H315-H319-H334-H335-H410-H302-H400
Precautionary statements  P280a-P405-P501a-P261-P280-P284-P304+P340-P305+P351+P338-P342+P311
Hazard Codes  Xn,N
Risk Statements  22-36/37/38-50/53
Safety Statements  13-24/25-46-60-61
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
RTECS  OV8740000
TSCA  Yes
HazardClass  6.1
PackingGroup  II

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