Home Categories Organic Chemistry Chromyl chloride
F407423

Chromyl chloride , 99.99 , 14977-61-8

Synonym(s):
Chromium(VI) dichloride dioxide;Chromium(VI) oxychloride;Dichlorochromium(VI) oxide

CAS NO.:14977-61-8

Empirical Formula: Cl2CrO2

Molecular Weight: 154.9

MDL number: MFCD00010951

EINECS: 239-056-8

Update time: 2022-07-08

PRODUCT Properties

Melting point: -96.5 °C (lit.)
Boiling point: 117 °C (lit.)
Density  1.911 g/mL at 25 °C (lit.)
Flash point: 117°C
solubility  reacts with H2O; soluble in ctc, chloroform,benzene
form  liquid
Specific Gravity 1.911
color  red
Water Solubility  Soluble in carbon tetrachloride, carbon disulfide, benzene, nitrobenzene, chloroform, and POCL3. Insoluble in water(Reacts).
Sensitive  Moisture Sensitive
Merck  14,2248
Dielectric constant 2.6(20℃)
Exposure limits ACGIH: TWA 0.0001 ppm; STEL 0.00025 ppm (Skin)
NIOSH: TWA 0.0002 mg/m3

Description and Uses

Chromyl chloride is a dark red fuming liquidwith a musty, burning odor. Molecular weight = 154.90;Specific gravity (H2O:1) =1.91 at 25℃; Boilingpoint =117℃; Freezing/Melting point =-96.5℃; Vaporpressure =20 mmHg at 25℃. Soluble in water(decomposes).

In organic oxidations and chlorinations; as a solvent for chromium oxide; in making chromium complexes and dyes

Safety

Symbol(GHS) 
GHS03,GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H271-H314-H317-H340-H350-H410
Precautionary statements  P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  O,T,C,N
Risk Statements  49-46-8-35-43-50/53-34-23/24/25-45
Safety Statements  53-45-60-61-36/37/39-27-26-17
RIDADR  UN 3244 8/PG 2
OEB E
OEL TWA: 0.001 mg Cr(VI)/m3
WGK Germany  3
RTECS  GB5775000
8-10-21
TSCA  Yes
HazardClass  8
PackingGroup  I
HS Code  2827499090

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