PRODUCT Properties
Melting point: | 42 °C(lit.) |
Boiling point: | 121 °C15 mm Hg(lit.) |
Density | 1.009 g/mL at 25 °C(lit.) |
vapor pressure | 0.1Pa at 20℃ |
refractive index | n |
Flash point: | >230 °F |
storage temp. | 2-8°C |
solubility | Chloroform (Slightly), Methanol (Slightly) |
pka | 12.80±0.20(Predicted) |
form | Oil |
color | Pale Yellow |
BRN | 1720667 |
LogP | -0.24 at 25℃ |
CAS DataBase Reference | 3031-66-1(CAS DataBase Reference) |
NIST Chemistry Reference | 3-Hexyne-2,5-diol(3031-66-1) |
EPA Substance Registry System | 3-Hexyne-2,5-diol (3031-66-1) |
Description and Uses
3-Hexyne-2,5-diol is a more or less solid yellow mass of crystals depending on the relative content of the meso form. It is miscible with water and polar solvents. 3-Hexyne-2,5-diol is produced by BASF from acetylene and acetaldehyde by the Reppe ethynylation method.
3-Hexyne-2,5-diol is used in the synthesis of hyperbrancehed poly([1,2,3]-triazoles. Also used in the synthesis of pyrazoles and thiopyrazoles.
Safety
Symbol(GHS) | GHS07 |
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
Hazard Codes | T |
Risk Statements | 25-36 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 2811 6.1/PG 3 |
WGK Germany | 2 |
RTECS | MR0175000 |
HazardClass | 6.1(b) |
PackingGroup | III |
Toxicity | mouse,LDLo,intraperitoneal,500mg/kg (500mg/kg),"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 378, 1952. |