Home Categories Chemical Reagents 2,2'-(Perfluorocyclohexa-2,5-diene-1,4-diylidene)dimalononitrile
BD8714931

2,2'-(Perfluorocyclohexa-2,5-diene-1,4-diylidene)dimalononitrile , 98% , 29261-33-4

Synonym(s):
(2,3,5,6-Tetrafluoro-2,5-cyclohexadiene-1,4-diylidene)dimalononitrile;7,7,8,8-Tetracyano-2,3,5,6-tetrafluoroquinodimethane;F4TCNQ

CAS NO.:29261-33-4

Empirical Formula: C12F4N4

Molecular Weight: 276.15

MDL number: MFCD00042382

Pack Size Price Stock Quantity
100mg RMB212.00 In Stock
250mg RMB400.00 In Stock
1g RMB1305.60 In Stock
5g RMB5168.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 285-290 °C(lit.)
Boiling point: -89.6±40.0 °C(Predicted)
Density  1.7075 (estimate)
storage temp.  Sealed in dry,Room Temperature
form  powder to crystal
color  Light yellow to Amber to Dark green
Water Solubility  insoluble
BRN  2157887
InChI InChI=1S/C12F4N4/c13-9-7(5(1-17)2-18)10(14)12(16)8(11(9)15)6(3-19)4-20
InChIKey IXHWGNYCZPISET-UHFFFAOYSA-N
SMILES C1(=C(C#N)C#N)C(F)=C(F)C(=C(C#N)C#N)C(F)=C1F |c:10,t:0|
CAS DataBase Reference 29261-33-4(CAS DataBase Reference)

Description and Uses

F4TCNQ is?one of the most widely used and most effective p-type dopants due to its strong electron-accepting ability and the extended?π?system. It has a deep LUMO level (-5.2 eV) which is energetically in the vicinity of the?HOMO level of many organic semiconductors. Doping is facilitated by charge transfer from the HOMO level of the host to the LUMO of the dopant molecule.?Pin devices with F4TCNQ doped 4,4',4''-tris(3-methylphenylphenylamino)triphenylamine (m-MTDATA) serving as the p-doped HTL show high luminance and efficiency at extremely low operating voltages: For instance, a luminance of 1000 cd/m2 is?reached at a voltage of 2.9 V .

F4-TCNQ is the p-type dopant for hole-only devices and field effect transistors with organic hole transport layers (HTL). It is used in the preparation of a bilayer structure of F4-TCNQ and pentacene to study improved thermoelectric performance of organic thin films.

Safety

Symbol(GHS) 
GHS06
Signal word  Danger
Hazard statements  H301+H311+H331
Precautionary statements  P280-P301+P310+P330-P302+P352+P312-P304+P340+P311
Hazard Codes  Xn,T
Risk Statements  36/37/38-20/21/22-23/24/25
Safety Statements  22-24/25-36/37/39-26-36/37
RIDADR  2811
WGK Germany  3
Hazard Note  Toxic
HazardClass  6.1(b)
PackingGroup  III
HS Code  29269090

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