Home Categories Organic Chemistry (((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine)
BD4748641

(((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine) , 99%99%ee , 37002-48-5

Synonym(s):
(+)-DIOP;(+)-DIOP, (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)-butane, (+)-1,4-Bis(diphenylphosphino)-1,4-dideoxy-2,3-O-isopropylidene-D-threitol;(S,S)-DIOP;(4S,5S)-4,5-Bis(diphenylphosphinomethyl)-2,2-dimethyl-1,3-dioxolane;(4S-trans)-[(2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene)]bis(diphenylphosphine)

CAS NO.:37002-48-5

Empirical Formula: C31H32O2P2

Molecular Weight: 498.54

MDL number: MFCD00009760

EINECS: 253-307-9

Pack Size Price Stock Quantity
250mg RMB148.00 In Stock
1g RMB386.40 In Stock
5g RMB1573.60 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 86-88 °C(lit.)
alpha  +26° (c 2.0, CHCl3)
Boiling point: 590.3±25.0 °C(Predicted)
storage temp.  Store below +30°C.
form  Powder
color  White
Water Solubility  Sparingly soluble in water at 25°C 2.1E-5 g/L.
Sensitive  Air Sensitive
BRN  1630280
InChIKey VCHDBLPQYJAQSQ-LOYHVIPDSA-N
CAS DataBase Reference 37002-48-5

Description and Uses

It is employed as a ligand for the in situ preparation of chiral hydrogenation catalysts. It also finds it application for the in situ preparation of chiral hydrogenation catalysts, ligand for Rh(I)-catalyzed asymmetric hydrogenation of enamides, 1,4-disilylation of α,β-unsaturated ketones, Heck reaction of alkenyl iodides, and hydroformylation of olefins.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
10-23
HS Code  29319090

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