1,1'-Bis(di-tert-butylphosphino)ferrocene-palladium dichloride , 98% , 95408-45-0

Synonym(s):
PdCl₂(dtbpf)

CAS NO.：95408-45-0

Empirical Formula: C26H38Cl2FeP2Pd

Molecular Weight: 645.7

MDL number: MFCD08064219

EINECS: 664-483-5

PRODUCT Properties

• Melting point: 203-208 °C
• storage temp.: -20°C
• solubility: Soluble in dichloromethane and chloroform. Partially soluble in acetone, alcohols, tertrahydrofuran and dioxane.
• form: crystal
• color: dark purple
• InChI: InChI=1S/2C13H19P.2ClH.Fe.Pd/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;;;;/h2*14H,1-6H3;2*1H;;/q;;;;+2;/p-2
• InChIKey: ORDFDLUOXDTTTD-UHFFFAOYSA-L
• SMILES: C(P1([Pd+2](P(C(C)(C)C)(C(C)(C)C)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]18C9=3)([Cl-])[Cl-])C(C)(C)C)(C)(C)C

Description and Uses

Coupling reactions, Suzuki couplings.Dichloro[1,1'-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Safety Statements: 24/25
• WGK Germany: 3
• HS Code: 28439000