Home Categories (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate
BD0788932

(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-iridium(I) hexafluorophosphate , 97% , 64536-78-3

Synonym(s):
(1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)-Ir(I) PF6;[Ir(cod)(PCy3)(py)]PF6;[Ir(cod)(PCy3)(py)]PF6;Crabtree’s catalyst;Iridium(I) hexafluorophosphate (1,5-Cyclooctadiene)-(pyridine)-(tricyclohexylphosphine) complex

CAS NO.:64536-78-3

Empirical Formula: C31H47F6IrNP2

Molecular Weight: 801.88

MDL number: MFCD00075097

Pack Size Price Stock Quantity
100mg RMB125.60 In Stock
250mg RMB236.80 In Stock
1g RMB759.20 In Stock
5g RMB3102.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 175 °C (dec.)(lit.)
Density  1.67 g/cm3
storage temp.  Inert atmosphere,Room Temperature
solubility  Chloroform (Slightly)
form  Crystalline Powder
color  Orange
Water Solubility  Slightly soluble in acetone, dichloromethane, ethanol and diethyl ether. Insoluble in water.
Sensitive  Moisture Sensitive
Merck  13,2594

Description and Uses

1,5-Cyclooctadiene(pyridine)(tricyclohexylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for hydrogenation of mono-, di-, tri-, and tetra-substituted substrates and the isomerization and hydroboration of alkenes. It is also used in isotope exchange reactions, especially the direct exchange of a hydrogen atom with its isotopes deuterium and tritium. Carbonyl groups are also known to direct the hydrogenation by the Crabtree catalyst is highly regioselective.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
10-21
TSCA  No
HS Code  29310099

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