Home Categories Chemical Reagents (R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine
BD0529445

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine , 98% , 158923-09-2

Synonym(s):
(1R)-1-(Dicyclohexylphosphino)-2-[(1R)-1-(diphenylphosphino)ethyl]ferrocene (acc to CAS);Josiphos SL-J004-1

CAS NO.:158923-09-2

Empirical Formula: C36H44FeP210*

Molecular Weight: 594.53

MDL number: MFCD00800280

Pack Size Price Stock Quantity
50mg RMB112.80 In Stock
100mg RMB146.40 In Stock
250mg RMB301.60 In Stock
1g RMB887.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

alpha  -100° ±5° (c 0.5, CHCl3)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
form  Powder
color  orange

Description and Uses

(R)-1-[(SP)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand:

  • To prepare iridium metal complex (IrIJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline.
  • In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
10
HS Code  29319090

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