m-Xylene solution , 1mg/mlinMethanol,forWaterAnalysis , 108-38-3
Synonym(s):
m-Xylene;1,3-Dimethylbenzene;m-Xylene
CAS NO.:108-38-3
Empirical Formula: C8H10
Molecular Weight: 106.17
MDL number: MFCD00008536
EINECS: 203-576-3
PRODUCT Properties
Melting point: | -48 °C (lit.) |
Boiling point: | 138-139 °C (lit.) |
Density | 0.868 g/mL at 25 °C (lit.) |
vapor density | 3.7 (vs air) |
vapor pressure | 16 mm Hg ( 37.7 °C) |
refractive index | n |
Flash point: | 77 °F |
storage temp. | 2-8°C |
solubility | Miscible with many organic solvents, including alcohol and ether |
form | Liquid |
pka | >15 (Christensen et al., 1975) |
color | Colorless |
Odor | Like benzene; characteristic aromatic. |
explosive limit | 1.1-7%(V) |
Odor Threshold | 0.041ppm |
Water Solubility | Miscible with organic solvents. Immiscible with water. |
Merck | 14,10081 |
BRN | 605441 |
Henry's Law Constant | 14.80 at 45.00 °C, 17.26.4 at 50.00 °C, 19.90 at 55.00 °C, 23.01.3 at 60.00 °C, 27.46.3 at 70.00 °C
(static headspace-GC, Park et al., 2004) |
Exposure limits | NIOSH REL: 100 ppm (435 mg/m3), STEL 150 ppm (655 mg/m3), IDLH 900
ppm; OSHA PEL: TWA 100 ppm; ACGIH TLV: TWA 100 ppm, STEL 150 ppm (adopted). |
Dielectric constant | 2.3999999999999999 |
InChIKey | IVSZLXZYQVIEFR-UHFFFAOYSA-N |
LogP | 3.16 at 20℃ |
Description and Uses
Xylene exists in three isomeric forms, ortho-,meta-, and para-xylene. Commercial xylene is a mixture ofthese three isomers and may also contain ethylbenzene aswell as small amounts of toluene, trimethylbenzene, phenol,thiophene, pyridine, and other nonaromatic hydrocarbons.m-Xylene is predominant in commercial xylene. The physical properties of the three isomers are as follows:Isomer MeltingPoint(℃)BoilingPoint(℃)FlashPoint(℃)LowerExpl.(%)UpperExpl.(%)AutoTemp.(℃)ortho- -25 144 32 0.9 6.7 463meta- -48 139 27 1.1 7.0 527para- 13 138 27 1.1 7.0 528
Meta-Xylene is used for the production of isophthalic acid, of agriculture chemicals as pharmaceuticals. It finds applications in paint and varnish removers and aerosol paint concentrates. Product Data Sheet
Safety
Symbol(GHS) | GHS02,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H226-H304-H312+H332-H315-H319-H335-H412 |
Precautionary statements | P210-P273-P280-P301+P310-P303+P361+P353-P331 |
Hazard Codes | Xn,T,F |
Risk Statements | 10-20/21-38-39/23/24/25-23/24/25-11-36/38 |
Safety Statements | 25-45-36/37-16-7 |
RIDADR | UN 1307 3/PG 3 |
OEB | A |
OEL | TWA: 100 ppm (435 mg/m3), STEL: 150 ppm (655 mg/m3) |
WGK Germany | 2 |
RTECS | ZE2275000 |
Autoignition Temperature | 982 °F |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | II |
HS Code | 29024200 |
Toxicity | LD50 orally in rats: 7.71 ml/kg (Smyth) |