Home Categories Organic Chemistry Tricyclohexylphosphine oxide
A8212112

Tricyclohexylphosphine oxide , 98% , 13689-19-5

CAS NO.:13689-19-5

Empirical Formula: C18H33OP

Molecular Weight: 296.43

MDL number: MFCD00014298

EINECS: 216-516-6

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5G RMB228.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 155-157°C
Boiling point: 466.6±12.0 °C(Predicted)
Density  1.00
storage temp.  Sealed in dry,Room Temperature
form  Crystalline
color  White to Almost white
Water Solubility  Soluble in most organic solvents. Insoluble in water.
CAS DataBase Reference 13689-19-5

Description and Uses

Tricyclohexylphosphine oxide is used as a ligand for a range of metal-catalyzed organic transformations. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.1 Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.

Safety

Symbol(GHS) 
GHS06
Signal word  Warning
Hazard statements  H301-H315-H319-H335
Precautionary statements  P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Risk Statements  36/37/38
Safety Statements  26-36/37/39
RIDADR  UN3464
HS Code  2931.39.0030
HazardClass  6.1
PackingGroup  III
Toxicity mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03087,

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