Home Categories Organic Chemistry Tricyclohexylphosphine oxide
A8212112

Tricyclohexylphosphine oxide , 98% , 13689-19-5

CAS NO.:13689-19-5

Empirical Formula: C18H33OP

Molecular Weight: 296.43

MDL number: MFCD00014298

EINECS: 216-516-6

Pack Size Price Stock Quantity
1G RMB84.00 In Stock
5G RMB228.00 In Stock
25G RMB854.40 In Stock
100G RMB3048.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 155-157°C
Boiling point: 466.6±12.0 °C(Predicted)
Density  1.00
storage temp.  Sealed in dry,Room Temperature
form  Crystalline
color  White to Almost white
Water Solubility  Soluble in most organic solvents. Insoluble in water.

Description and Uses

Tricyclohexylphosphine oxide is used as a ligand for a range of metal-catalyzed organic transformations. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.1 Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.

Safety

Symbol(GHS) 
GHS06
Signal word  Warning
Hazard statements  H301-H315-H319-H335
Precautionary statements  P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Risk Statements  36/37/38
Safety Statements  26-36/37/39
RIDADR  UN3464
HS Code  2931.39.0030
HazardClass  6.1
PackingGroup  III
Toxicity mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03087,

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