Trimethylsilyl Isocyanate , >80.0%(GC) , 1118-02-1

Synonym(s):
Isocyanatotrimethylsilane

CAS NO.：1118-02-1

Empirical Formula: C4H9NOSi

Molecular Weight: 115.21

MDL number: MFCD00001993

EINECS: 214-256-8

PRODUCT Properties

• Melting point: -49°C
• Boiling point: 90-92 °C(lit.)
• Density: 0.851 g/mL at 25 °C(lit.)
• refractive index: n20/D 1.396(lit.)
• Flash point: -2 °C
• storage temp.: 2-8°C
• solubility: Miscible with ethers and o-dichlorobenzene.
• form: clear liquid
• Specific Gravity: 0.867
• color: Colorless to Almost colorless
• Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
• Sensitive: Moisture Sensitive
• BRN: 1744962

Description and Uses

Trimethylsilyl isocyanate is used in the preparation of 1-unsubstituted 4-(dialkylamino) imidazolin-2-ones. It finds application in the carbamoylation of aromatic hydrocarbons and alcohols. It is also used in the preparation of primary amides from Grignard reagents. Further, it is used in the synthesis of cyclic imides. It is also utilized for the synthesis of trifluoroacetyl isocyanate and cyclic imides. In addition to this, it is employed in the conversion of isocyanates to carbodiimides using cyclopentadienyl Mn(CO)3 catalysis.

Safety

• Symbol(GHS): GHS02,GHS06,GHS08
• Signal word: Danger
• Hazard statements: H225-H317-H319-H331-H334-H335
• Precautionary statements: P210-P233-P280-P303+P361+P353-P304+P340+P311-P305+P351+P338
• Hazard Codes: F,T
• Risk Statements: 11-23-36/37-42
• Safety Statements: 23-26-36/37/39-45
• RIDADR: UN 2478 3/PG 2
• WGK Germany: 3
• F: 10-19-21
• TSCA: Yes
• HazardClass: 3
• PackingGroup: II
• HS Code: 29319090