Home Categories Organic Chemistry Tris(2,6-dimethoxyphenyl)phosphine
A7871512

Tris(2,6-dimethoxyphenyl)phosphine , >97.0%(HPLC) , 85417-41-0

Synonym(s):
DMPP

CAS NO.:85417-41-0

Empirical Formula: C24H27O6P

Molecular Weight: 442.44

MDL number: MFCD00192558

Pack Size Price Stock Quantity
1g RMB68.00 In Stock
5g RMB192.00 In Stock
25G RMB528.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 145-147 °C(lit.)
Boiling point: 566.4±50.0 °C(Predicted)
storage temp.  Sealed in dry,Room Temperature
solubility  very faint turbidity in hot Methanol
form  Powder
color  white to off-white
Sensitive  air sensitive
CAS DataBase Reference 85417-41-0

Description and Uses

Catalyst for:

  • Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
  • Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
  • Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
  • Oxycylizations of allendiols
  • Enantioselective aldol reactions
  • Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280a-P304+P340-P405-P501a-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
TSCA  No
HS Code  29310099

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