Triruthenium dodecacarbonyl , 99% , 15243-33-1

Synonym(s):
Ruthenium carbonyl;tri-Ruthenium dodecacarbonyl

CAS NO.：15243-33-1

Empirical Formula: C12O12Ru3

Molecular Weight: 639.33

MDL number: MFCD00011209

EINECS: 239-287-4

PRODUCT Properties

• Melting point: 150 °C
• storage temp.: Inert atmosphere,Room Temperature
• solubility: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
• form: crystal
• color: orange

Description and Uses

Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H332
• Precautionary statements: P261-P271-P304+P340+P312
• Hazard Codes: F,Xn
• Risk Statements: 11-20-2017/11/20
• Safety Statements: 24/25
• RIDADR: 1325
• WGK Germany: 3
• Hazard Note: Flammable/Harmful
• TSCA: Yes
• HazardClass: 6.1
• PackingGroup: II
• HS Code: 28439000