Home Categories Organic Chemistry Tri(o-tolyl)phosphine
A7716912

Tri(o-tolyl)phosphine , 97% , 6163-58-2

Synonym(s):
P(o-tol)3;Tri(o-tolyl)-phosphine;Tris(o-tolyl)phosphine

CAS NO.:6163-58-2

Empirical Formula: C21H21P

Molecular Weight: 304.37

MDL number: MFCD00008514

EINECS: 228-193-9

Pack Size Price Stock Quantity
1G RMB23.20 In Stock
5G RMB42.40 In Stock
25G RMB86.40 In Stock
100G RMB336.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 123-125 °C(lit.)
Boiling point: 412.4±44.0 °C(Predicted)
Density  1.16[at 20℃]
vapor pressure  0Pa at 20℃
Flash point: 198°C (388°F)
storage temp.  Store below +30°C.
solubility  Chloroform, Ethyl Acetate
form  Crystalline Powder
color  White
Water Solubility  Soluble in alcohol. Slightly soluble in cold water. Insoluble in water.
Sensitive  air sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN  661212
InChIKey COIOYMYWGDAQPM-UHFFFAOYSA-N
LogP 7.2
CAS DataBase Reference 6163-58-2(CAS DataBase Reference)
NIST Chemistry Reference Phosphine, tris(2-methylphenyl)-(6163-58-2)
EPA Substance Registry System Phosphine, tris(2-methylphenyl)- (6163-58-2)

Description and Uses

Tris(o-tolyl)phosphine is an organophosphorus compound. This compound is a white, water-insoluble solid that is soluble in organic solvents. In solution, it slowly converts to the phosphine oxide. As a phosphine ligand, it has a wide cone angle of 194°. Consequently, it tends to cyclometalate when treated with metal halides and metal acetates. Complexes of this ligand are common in homogeneous catalysis.

Tri(o-tolyl)phosphine is used in a ruthenium-catalyzed direct amination of alcohols. It is also used in Suzuki reaction. Further, it is used in the preparation of tri-ortho-phosphinselenide by reacting with selenium as a reagent. In addition to this, it acts as a ligand in coordination chemistry.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
10-23
TSCA  Yes
HS Code  29319090

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