Tri(o-tolyl)phosphine , 97% , 6163-58-2

Synonym(s):
P(o-tol)₃;Tri(o-tolyl)-phosphine;Tris(o-tolyl)phosphine

CAS NO.：6163-58-2

Empirical Formula: C21H21P

Molecular Weight: 304.37

MDL number: MFCD00008514

EINECS: 228-193-9

PRODUCT Properties

• Melting point: 123-125 °C(lit.)
• Boiling point: 412.4±44.0 °C(Predicted)
• Density: 1.16[at 20℃]
• vapor pressure: 0Pa at 20℃
• Flash point: 198°C (388°F)
• storage temp.: Store below +30°C.
• solubility: Chloroform, Ethyl Acetate
• form: Crystalline Powder
• color: White
• Water Solubility: Soluble in alcohol. Slightly soluble in cold water. Insoluble in water.
• Sensitive: air sensitive
• Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
• BRN: 661212
• InChIKey: COIOYMYWGDAQPM-UHFFFAOYSA-N
• LogP: 7.2

Description and Uses

Tris(o-tolyl)phosphine is an organophosphorus compound. This compound is a white, water-insoluble solid that is soluble in organic solvents. In solution, it slowly converts to the phosphine oxide. As a phosphine ligand, it has a wide cone angle of 194°. Consequently, it tends to cyclometalate when treated with metal halides and metal acetates. Complexes of this ligand are common in homogeneous catalysis.

Tri(o-tolyl)phosphine is used in a ruthenium-catalyzed direct amination of alcohols. It is also used in Suzuki reaction. Further, it is used in the preparation of tri-ortho-phosphinselenide by reacting with selenium as a reagent. In addition to this, it acts as a ligand in coordination chemistry.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H315-H319-H335
• Precautionary statements: P261-P280a-P304+P340-P305+P351+P338-P405-P501a
• Hazard Codes: Xi
• Risk Statements: 36/37/38
• Safety Statements: 26-36-37/39
• WGK Germany: 3
• F: 10-23
• TSCA: Yes
• HS Code: 29319090