A7702412
Tetrabutylphosphonium bromide , 98% , 3115-68-2
CAS NO.：3115-68-2
Empirical Formula: C16H36BrP
Molecular Weight: 339.33
MDL number: MFCD00011853
EINECS: 221-487-8
| Pack Size | Price | Stock | Quantity |
| 5g | RMB24.80 | In Stock |
|
| 25G | RMB79.20 | In Stock |
|
| 100G | RMB238.40 | In Stock |
|
| 250g | RMB559.20 | In Stock |
|
| 500G | RMB934.40 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 100-103 °C(lit.) |
| Density | 1.8[at 20℃] |
| vapor pressure | 0.018Pa at 25℃ |
| Flash point: | 290 °C |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | crystal |
| color | white |
| Water Solubility | ca 70 g/100 mL |
| Sensitive | Hygroscopic |
| BRN | 4160474 |
| Stability: | hygroscopic |
| InChIKey | JRMUNVKIHCOMHV-UHFFFAOYSA-M |
| LogP | -0.44 at 23℃ |
Description and Uses
Tetra-n-butylphosphonium bromide is used as a phase-transfer catalyst at high temperatures, at which nitrogen analogues tend to undergo elimination e.g. as catalyst for the dealkoxycarbonylation of malonates and -keto esters by heating in stearic acid. used as an ionic liquid solvent in the regioselective O-alkylation of C/O ambident nucleophiles. It is a synthetic reagent used in proteomics research.
Safety
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H290-H302-H311-H317-H318-H361fd-H411 |
| Precautionary statements | P273-P280-P301+P312-P302+P352+P312-P305+P351+P338-P308+P313 |
| Hazard Codes | Xn,T,Xi |
| Risk Statements | 21/22-36/37/38-24-20/21/22 |
| Safety Statements | 26-37/39-45-36/37/39-28A-36 |
| RIDADR | UN 3464 6.1/PG 3 |
| WGK Germany | 3 |
| RTECS | TA2417000 |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29310095 |
| Toxicity | mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03131, |
