Home Categories Organic Chemistry Titanium ethoxide
A7695612

Titanium ethoxide , 33-35%TiO2 , 3087-36-3

Synonym(s):
Tetraethyl orthotitanate;Tetraethyl titanate

CAS NO.:3087-36-3

Empirical Formula: C8H20O4Ti

Molecular Weight: 228.11

MDL number: MFCD00009071

EINECS: 221-410-8

Update time: 2022-07-08

PRODUCT Properties

Melting point: 54°C
Boiling point: 150-152 °C10 mm Hg(lit.)
Density  1.088 g/mL at 25 °C(lit.)
vapor pressure  57.26hPa at 19.6℃
refractive index  n20/D 1.505(lit.)
Flash point: 84 °F
storage temp.  2-8°C
solubility  Soluble in organic solvents.
form  Liquid
Specific Gravity 1.107 (20℃)
color  Pale yellow
Water Solubility  reacts
Sensitive  Moisture Sensitive
BRN  3678992
Exposure limits ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability: Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKey JMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP -0.3 at 25℃

Description and Uses

Titanium(IV) ethoxide can be used:

  • As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
  • As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
  • As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Safety

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H319
Precautionary statements  P210-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38-67
Safety Statements  26-37/39-16
RIDADR  UN 1993 3/PG 3
WGK Germany  3
3-10-21
TSCA  Yes
HazardClass  4.1
PackingGroup  III
HS Code  29051900

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