Home Categories Organic Chemistry Trioctylphosphine oxide
A7688312

Trioctylphosphine oxide , 98% , 78-50-2

Synonym(s):
(Oct)3PO;Thorium ionophore I;TOPO;Trioctylphosphinoxide

CAS NO.:78-50-2

Empirical Formula: C24H51OP

Molecular Weight: 386.63

MDL number: MFCD00002083

EINECS: 201-121-3

Pack Size Price Stock Quantity
1g RMB31.20 In Stock
5g RMB75.20 In Stock
25G RMB263.20 In Stock
100G RMB798.40 In Stock
500G RMB3439.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 50-52 °C(lit.)
Boiling point: 201-202 °C2 mm Hg(lit.)
Density  0,88 g/cm3
vapor pressure  0.004Pa at 50℃
Flash point: >230 °F
storage temp.  Store below +30°C.
solubility  <1g/l
form  Crystalline Powder, Crystals or Flakes
color  White to slightly yellow
Water Solubility  Insoluble
BRN  1796648
Stability: Stable. Incompatible with strong oxidizing agents.
LogP 9.54
CAS DataBase Reference 78-50-2(CAS DataBase Reference)
EPA Substance Registry System Phosphine oxide, trioctyl- (78-50-2)

Description and Uses

Catalyst in:

  • Preparation of tetradentate planar-chiral hydroxy-substituted ferrocenecarboxaldimine Schiff base ligands
  • Reactions of allyl esters with hydrosilanes
  • Asymmetric cyanosilylation of aldehydes
  • Preparation of chlorothiol formates from thiols and phosgene

Safety

Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H315-H318-H412
Precautionary statements  P264-P273-P280-P302+P352-P305+P351+P338-P332+P313
Hazard Codes  Xi,Hazard
Risk Statements  38-41-50/53-34
Safety Statements  26-36/39-39-61-60-45-36/37/39
RIDADR  3261
WGK Germany  2
RTECS  SZ1662500
Autoignition Temperature 270 °C
TSCA  Yes
PackingGroup  II
HS Code  29310095
HS Code  32019090
Toxicity LD50 orally in Rabbit: > 10000 mg/kg LD50 dermal Rat 2830 mg/kg

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