Ethylacetoacetate , 10mMinDMSO , 141-97-9
Synonym(s):
Acetoacetic ester;EAA;EAA, Acetoacetic acid ethyl ester;Ethyl 3-oxobutanoate;Ethyl acetoacetate
CAS NO.：141-97-9
Empirical Formula: C6H10O3
Molecular Weight: 130.14
MDL number: MFCD00009199
EINECS: 205-516-1
| Pack Size | Price | Stock | Quantity |
| 1ml | RMB159.20 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | −43 °C(lit.) |
| Boiling point: | 181 °C(lit.) |
| Density | 1.029 g/mL at 20 °C(lit.) |
| vapor density | 4.48 (vs air) |
| vapor pressure | 1 mm Hg ( 28.5 °C) |
| FEMA | 2415 | ETHYL ACETOACETATE |
| refractive index | n |
| Flash point: | 185 °F |
| storage temp. | Store below +30°C. |
| solubility | 116 g/L (20°C) |
| pka | 11(at 25℃) |
| form | Liquid |
| Specific Gravity | 1.027～1.035 (20/4℃) |
| color | APHA: ≤15 |
| Relative polarity | 0.577 |
| PH | 4.0 (110g/l, H2O, 20℃) |
| Odor | Agreeable, fruity. |
| explosive limit | 1.0-54%(V) |
| Odor Type | fruity |
| Water Solubility | 116 g/L (20 ºC) |
| Merck | 14,3758 |
| JECFA Number | 595 |
| BRN | 385838 |
| Dielectric constant | 15.0（Ambient） |
| Stability: | Stable. Incompatible with acids, bases, oxidizing agents, reducing agents, alkali metals. Combustible. |
| InChIKey | XYIBRDXRRQCHLP-UHFFFAOYSA-N |
| LogP | 0.8 at 20℃ |
| CAS DataBase Reference | 141-97-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Butanoic acid, 3-oxo-, ethyl ester(141-97-9) |
| EPA Substance Registry System | Ethyl acetoacetate (141-97-9) |
Description and Uses
The organic compound ethyl acetoacetate (EAA) is the ethyl ester of acetoacetic acid. It is mainly used as a chemical intermediate in the production of a wide variety of compounds, such as amino acids, analgesics, antibiotics, antimalarial agents, antipyrine and amino pyrine, and vitamin B1; as well as the manufacture of dyes, inks, lacquers, perfumes, plastics, and yellow paint pigments. Alone, it is used as a flavoring for food.
Ethyl acetoacetate is used as an intermediate in organic synthesis and as a co-promoter for unsaturated polyester resins. It is widely used in the production of dyes, inks, perfumes, plastics and flavoring agents. It is an important starting material for the syntheses of alpha-substituted acetoacetic esters and cyclic compounds like pyrazole, pyrimidine and coumarin derivatives. It acts as an intermediate in the synthesis of vitamins and pharmaceuticals. It finds application as a formaldehyde scavenger.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H227-H319-H303 |
| Precautionary statements | P210e-P280a-P305+P351+P338-P337+P313-P501a-P210-P264-P280-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501 |
| Hazard Codes | Xi |
| Risk Statements | 36 |
| Safety Statements | 26-24/25 |
| RIDADR | UN 1993 |
| WGK Germany | 1 |
| RTECS | AK5250000 |
| Autoignition Temperature | 580 °F |
| TSCA | Yes |
| HazardClass | 3.2 |
| PackingGroup | III |
| HS Code | 29183000 |
| Hazardous Substances Data | 141-97-9(Hazardous Substances Data) |
| Toxicity | LD50 orally in rats: 3.98 g/kg (Smyth) |
