Home Categories (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.
A7399712

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. , ≥97% , 380230-02-4

Synonym(s):
(+)-N,N-Bis[(1S)-1-phenylethyl]- dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin- 4-amine, (11bR)

CAS NO.:380230-02-4

Empirical Formula: C36H30NO2P

Molecular Weight: 539.6

MDL number: MFCD04117688

Pack Size Price Stock Quantity
5MG RMB153.60 In Stock
25MG RMB394.40 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 88-89 °C
Boiling point: 710.7±63.0 °C(Predicted)
alpha  +13.1° (c 1.01, CHCl3)
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
pka -0.57±0.20(Predicted)
form  Powder
color  off-white
Sensitive  moisture sensitive
InChIKey LKZPDRCMCSBQFN-UIOOFZCWSA-N

Description and Uses

The product may be used as a ligand in:

  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

Safety

Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3

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