Home Categories Chemical Reagents (S)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororuthenium
A7397612

(S)-[2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]dichlororuthenium , 97% , 134524-84-8

Synonym(s):
(S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine]ruthenium complex;(S)-BINAP dichlororuthenium complex;[(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium

CAS NO.:134524-84-8

Empirical Formula: C44H32Cl2P2Ru

Molecular Weight: 794.65

MDL number: MFCD01073794

EINECS: 634-379-4

Pack Size Price Stock Quantity
50MG RMB87.20 In Stock
250MG RMB228.80 In Stock
1G RMB579.20 In Stock
5G RMB1776.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: >300 ºC
storage temp.  under inert gas (nitrogen or Argon) at 2-8°C
solubility  Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form  Powder
color  orange
Sensitive  air sensitive
Stability: Air Sensitive, Moisture Sensitive

Description and Uses

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39-36/37
WGK Germany  3
HS Code  28439000

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