Solasodine , 126-17-0
Synonym(s):
Solasodin;(-)-Solasodine;(3β,22α,25R)-Spirosol-5-en-3-ol;Purapuridine;Solancarpidine
CAS NO.：126-17-0
Empirical Formula: C27H43NO2
Molecular Weight: 413.64
MDL number: MFCD00037844
EINECS: 204-774-2
| Pack Size | Price | Stock | Quantity |
| 50MG | RMB411.20 | In Stock |
|
| 100MG | RMB699.20 | In Stock |
|
| 250MG | RMB1599.20 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | 200-202° |
| alpha | D25 -98° (c = 0.14 in methanol); D -113° (CHCl3) |
| Boiling point: | 532.75°C (rough estimate) |
| Density | 1.0159 (rough estimate) |
| refractive index | 1.6400 (estimate) |
| storage temp. | 2-8°C |
| solubility | DMSO: soluble0.5mg/mL, clear (warmed) |
| pka | pKb 6.30(at 25℃) |
| form | powder |
| color | white to beige |
| optical activity | [α]/D -88 to -98°, c = 0.2 in methanol |
| InChIKey | KOZCINYDCJVLDW-GCGBSLFCSA-N |
| CAS DataBase Reference | 126-17-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Solasodine(126-17-0) |
Description and Uses
There is still some doubt as to whether this base occurs as such in Solanum aviculare and S. xanthocarpum or whether it is an artifact formed from Sola_x0002_sonine (q.v.) during the extraction process. The base is laevorotatory having [α]20D - 92.4° (C6H6) and the following salts and derivatives have been prepared: hydrochloride, m.p. 314°C; hydriodide, m.p. 293°C; oxalate, m.p. 248°C; tartrate, m.p. 222°C; picrate, m.p. 1.4l-2°C; picrolonate, m.p. 234°C; acetyl derivative, m.p. 195°C; benzoyl compound, m.p. 2l6-7°C and the 3:5-dinitrobenzoyl derivative, m.p. 191.5-193°C. The alkaloid forms a sparingly soluble digitonide and yields Diels's hydrocarbon on selenium dehydrogenation.
A potentially useful precursor.
Safety
| Safety Statements | 22-24/25 |
| RTECS | WF1300000 |
| Hazardous Substances Data | 126-17-0(Hazardous Substances Data) |
