Home Categories Inorganic chemistry Strontium sulfate
A7324012

Strontium sulfate , CP , 7759-02-6

Synonym(s):
Celestite

CAS NO.:7759-02-6

Empirical Formula: O4SSr

Molecular Weight: 183.68

MDL number: MFCD00036274

EINECS: 231-850-2

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250G RMB44.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 1606 °C (lit.)
Density  3.96 g/mL at 25 °C (lit.)
RTECS  WT1210000
storage temp.  Inert atmosphere,Room Temperature
solubility  aqueous acid: slightly soluble(lit.)
form  powder
color  White
Water Solubility  Soluble in dilute hydrochloric acid and nitric acid . Slightly soluble in water < 0.01 g/L . Insoluble in ethanol and alkalis.
Merck  14,8848
Solubility Product Constant (Ksp) pKsp: 6.46
CAS DataBase Reference 7759-02-6(CAS DataBase Reference)
EPA Substance Registry System Sulfuric acid, strontium salt (1:1) (7759-02-6)

Description and Uses

Strontium sulfate has the molecular formula of SrSO4 and the molecular weight of 183.6842 g/mol. It can be prepared by the reaction of sodium sulfate and strontium chloride:
Na2SO4+SrCl2?SrSO4+2NaCl
Strontium sulfate occurs in nature as “celestite” and is mined from its natural deposits. Also, the sulfate can be made by reacting strontium oxide, hydroxide, or carbonate with dilute hydrochloric acid:
SrO+H2SO4?SrSO4+H2O
SrCO3+H2SO4?SrSO4+CO2+H2O
No hydrates are known.Its hardness is 3.3 Mohs. It melts at 1608°C. Its solubility in water is 0.015 g/100 ml at 25°C and 0.014 g at 35°C. It is insoluble in ethanol and acetone, but slightly soluble in acids and alkalis. It is soluble in alkali chloride solutions. The heat of formation, △Hf, is –1453 kJ/mol with an entropy value, S0, of 117.0 J/mol K. Its Mohs Hardness is 3.0–3.5. A water solution has a pH of 7.5. Its specific gravity ranges from 3.8 to 4.0 g/cm3.Pure strontium sulfate precipitate consists of single crystals, about some tens of microns long, with distinctly visible growth steps. Crystals grown with polyvinyl sulfonate in stirred solutions show a striking change of habit: they are sponge-like structures, composed of minute crystallites, of size in the nanometer range. Crystallized strontium sulfate is utilized by a small group of protozoa as a main constituent of their skeleton. It is sometimes used to impart iridescence to glass and pottery glazes or used as a fining agent in crystal glass.
There is very little demand for this salt in industry. It is available in limited quantities commercially.

Widely applied in the manufacturing of Barium Salts, pigments, special glass, printing inks, paints, filler for textiles, linoleum, paper, rubber, base for color lakes, as pigment and white lead substitutes.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Safety Statements  22-24/25
WGK Germany  3
TSCA  Yes
HS Code  28332990

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