Home Categories Inorganic chemistry Sodium peroxide
A7254712

Sodium peroxide , ACSreagent,≥93.0% , 1313-60-6

Synonym(s):
Sodium peroxide;Sodium superoxide

CAS NO.:1313-60-6

Empirical Formula: Na2O2

Molecular Weight: 77.98

MDL number: MFCD00003497

EINECS: 215-209-4

Update time: 2022-07-08

PRODUCT Properties

Melting point: 460 °C (dec.)(lit.)
Boiling point: 657°C
Density  2.8
vapor pressure  0.001Pa at 20℃
Flash point: 657°C
storage temp.  Store at +15°C to +25°C.
solubility  Soluble in acid. Insoluble in alkali.
form  beads (small)
color  Yellow
Specific Gravity 2.805
Odor Odorless
PH Range 12.8
PH 12.8 (100g/l, H2O, 20℃)
Water Solubility  Soluble in water, forming NaOH and H{2}O{2}. Soluble in acid. Insoluble in alkali.
Sensitive  Air Sensitive & Hygroscopic
Merck  14,8655
Dielectric constant 2.7(Ambient)
Stability: Reacts violently with water. Contact with combustible materials may cause fire or explosion. Incompatible with strong oxidizing agents, alcohols, organic materials, acids, powdered metals. Absorbs carbon dioxide from the air.

Description and Uses

Sodium peroxide has a molecular formula of Na2O2 and is an inorganic peroxide salt. It is a yellowish-white powder that turns yellow when heated. Sodium peroxide absorbs water and carbon dioxide from the air and is soluble in cold water. It is a strong oxidizing agent, is corrosive and can cause burns to the eyes and skin, and is also toxic by ingestion and inhalation. Sodium peroxide is water reactive and a dangerous fire and explosion risk in contact with water, alcohol, or acids. Sodium peroxide forms self-igniting mixtures with powdered metals and organic materials. It is incompatible with ethyl or methyl alcohol, glacial acetic acid, carbon disulfide, glycerin, ethylene glycol, and ethyl acetate. The four-digit UN identification number is 1504. The NFPA 704 designation is health 3, flammability 0, and reactivity 1. The 704 diamond has the prefix “oxy” in the white space at the bottom. It is used as bleach and as an oxygen-generating material for diving bells and submarines.

Bleaching animal and vegetable fibers, feathers, bones, ivory, wood, wax, sponges, coral; rendering air charged with CO2 respirable as in torpedo boats, submarines, diving bells, etc.; purifying air in sick rooms; dyeing and printing textiles; chemical analysis. General oxidizing agent.

Safety

Symbol(GHS) 
GHS03,GHS05
Signal word  Danger
Hazard statements  H271-H314
Precautionary statements  P210-P220-P260-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  O,C
Risk Statements  8-35
Safety Statements  8-27-39-45
RIDADR  UN 1504 5.1/PG 1
WGK Germany  1
RTECS  WD3450000
3-9-23
TSCA  Yes
HS Code  2815 30 00
HazardClass  5.1
PackingGroup  I

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