(R)-(+)-Glycidol , 98% , 57044-25-4

Synonym(s):
(R)-(+)-Oxirane-2-methanol

CAS NO.：57044-25-4

Empirical Formula: C3H6O2

Molecular Weight: 74.08

MDL number: MFCD00074873

EINECS: 404-660-4

PRODUCT Properties

• Boiling point: 56-57 °C11 mm Hg(lit.)
• Density: 1.116 g/mL at 20 °C(lit.)
• refractive index: n20/D 1.43(lit.)
• Flash point: 178 °F
• storage temp.: -20°C
• Water Solubility: Completely miscible in water
• solubility: Chloroform (Slightly), DMSO (Slightly)
• pka: 14.62±0.10(Predicted)
• color: Colorless to Light yellow
• optical activity: [α]23/D +15°, neat
• BRN: 79782
• Stability: Moisture Sensitive
• InChIKey: CTKINSOISVBQLD-GSVOUGTGSA-N

Description and Uses

(R)-(+)-Glycidol may be used in the following synthesis:

• heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
• enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
• 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
• (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
• 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
• chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Safety

• Symbol(GHS): GHS02,GHS05,GHS06,GHS07,GHS08
• Signal word: Danger
• Hazard statements: H227-H315-H319-H335-H361-H370-H373-H242-H302-H312-H314-H331-H341-H350-H360F-H302+H312-H330
• Precautionary statements: P201-P280-P305+P351+P338-P310-P260-P284-P202-P210-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P311-P305+P351+P338+P337+P313-P307+P311-P403+P233-P405-P501
• Hazard Codes: T,E
• Risk Statements: 45-60-2-21/22-23-34-68-41-37/38
• Safety Statements: 53-45-36/37/39-26
• RIDADR: UN 2922 8/PG 2
• WGK Germany: 3
• RTECS: RR0508000
• F: 10-21
• HazardClass: 6.1
• PackingGroup: Ⅲ
• HS Code: 29109000