Home Categories Chemical Reagents (R)-(+)-Glycidol
A7125612

(R)-(+)-Glycidol , 98% , 57044-25-4

Synonym(s):
(R)-(+)-Oxirane-2-methanol

CAS NO.:57044-25-4

Empirical Formula: C3H6O2

Molecular Weight: 74.08

MDL number: MFCD00074873

EINECS: 404-660-4

Pack Size Price Stock Quantity
1G RMB32.00 In Stock
5G RMB103.20 In Stock
25G RMB432.00 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 56-57 °C11 mm Hg(lit.)
Density  1.116 g/mL at 20 °C(lit.)
refractive index  n20/D 1.43(lit.)
Flash point: 178 °F
storage temp.  -20°C
Water Solubility  Completely miscible in water
solubility  Chloroform (Slightly), DMSO (Slightly)
pka 14.62±0.10(Predicted)
color  Colorless to Light yellow
optical activity [α]23/D +15°, neat
BRN  79782
Stability: Moisture Sensitive
InChIKey CTKINSOISVBQLD-GSVOUGTGSA-N
CAS DataBase Reference 57044-25-4(CAS DataBase Reference)
NIST Chemistry Reference Oxiranemethanol, (R)-(57044-25-4)

Description and Uses

(R)-(+)-Glycidol may be used in the following synthesis:

  • heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
  • enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
  • 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
  • (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
  • 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
  • chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Safety

Symbol(GHS) 
GHS02,GHS05,GHS06,GHS07,GHS08
Signal word  Danger
Hazard statements  H227-H315-H319-H335-H361-H370-H373-H242-H302-H312-H314-H331-H341-H350-H360F-H302+H312-H330
Precautionary statements  P201-P280-P305+P351+P338-P310-P260-P284-P202-P210-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P311-P305+P351+P338+P337+P313-P307+P311-P403+P233-P405-P501
Hazard Codes  T,E
Risk Statements  45-60-2-21/22-23-34-68-41-37/38
Safety Statements  53-45-36/37/39-26
RIDADR  UN 2922 8/PG 2
WGK Germany  3
RTECS  RR0508000
10-21
HazardClass  6.1
PackingGroup 
HS Code  29109000

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