Ruthenium(III) chloride anhydrous , Rucontent45-55% , 10049-08-8

CAS NO.：10049-08-8

Empirical Formula: Cl3Ru

Molecular Weight: 207.43

MDL number: MFCD00011208

EINECS: 233-167-5

PRODUCT Properties

• Melting point: 500 °C
• Density: 3.11 g/mL at 25 °C (lit.)
• storage temp.: Keep in dark place,Inert atmosphere,Room temperature
• solubility: insoluble in H2O; slightly soluble in ethanol
• form: Powder or Crystals
• color: Black
• Water Solubility: INSOLUBLE
• Sensitive: Hygroscopic
• Crystal Structure: AlCl3 type
• crystal system: Monoclinic
• Merck: 14,8302
• Space group: C2/m
• Lattice constant:
  • a/nm: 0.606
  • b/nm: 1.036
  • c/nm: 0.598
  • α/o: 90
  • β/o: 109.2
  • γ/o: 90
  • V/nm3: 0.355
• Stability: Stable. Incompatible with zinc. Protect from moisture.
• InChI: InChI=1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
• InChIKey: YBCAZPLXEGKKFM-UHFFFAOYSA-K
• SMILES: [Ru](Cl)(Cl)Cl

Description and Uses

Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.

Safety

• Symbol(GHS): GHS05,GHS07,GHS09
• Signal word: Danger
• Hazard statements: H302-H314-H411
• Precautionary statements: P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
• Hazard Codes: C
• Risk Statements: 34-52/53-22
• Safety Statements: 26-36/37/39-45-61
• RIDADR: UN 3260 8/PG 2
• WGK Germany: 2
• RTECS: VM2650000
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• HS Code: 28439000