A6846612
Potassium trimethylsilanolate , ≥90%, industrial grade , 10519-96-7
Synonym(s):
Trimethylsilanol potassium salt
CAS NO.:10519-96-7
Empirical Formula: C3H9KOSi
Molecular Weight: 128.29
MDL number: MFCD00013421
EINECS: 234-062-7
Pack Size | Price | Stock | Quantity |
5G | RMB59.20 | In Stock |
|
10G | RMB95.20 | In Stock |
|
25G | RMB173.60 | In Stock |
|
100G | RMB552.80 | In Stock |
|
500G | RMB1960.80 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 135-138 °C (lit.) |
Density | 0.91 |
Flash point: | -14°C (7°F) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | DMSO (Springly), Methanol (Slightly) |
form | powder |
color | White |
Specific Gravity | 0.91 |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 3560282 |
InChI | InChI=1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1 |
InChIKey | LBKJNHPKYFYCLL-UHFFFAOYSA-N |
SMILES | [Si]([O-])(C)(C)C.[K+] |
EPA Substance Registry System | Silanol, trimethyl-, potassium salt (10519-96-7) |
Description and Uses
Potassium trimethylsilanolate can be used as a reagent in the:
- Hydrolysis of nitriles to primary amides.
- Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates.
- Synthesis of E-alkenes, and nitrocefin.
It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.
Safety
Symbol(GHS) | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P303+P361+P353-P305+P351+P338 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3263 8/PG 2 |
WGK Germany | 3 |
F | 3-10-21 |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | III |
HS Code | 29319090 |