A6781712
Pentamethylcyclopentadienylrhodium(III) chloride dimer , 99% , 12354-85-7
Synonym(s):
Pentamethylcyclopentadienylrhodium(III) chloride dimer;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium;1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex;Bis(dichloro(pentamethylcyclopentadienyl)rhodium);Bis(pentamethylcyclopentadienylrhodium dichloride)
CAS NO.：12354-85-7
Empirical Formula: C20H30Cl4Rh210*
Molecular Weight: 618.08
MDL number: MFCD00061552
| Pack Size | Price | Stock | Quantity |
| 100MG | RMB1679.20 | In Stock |
|
| 250MG | RMB2879.20 | In Stock |
|
| 500mg | RMB5599.20 | In Stock |
|
| 1G | RMB7999.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | >300°C |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | crystal |
| color | red |
| Water Solubility | Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether |
| Stability: | Hygroscopic |
Description and Uses
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302+H312+H332-H315 |
| Precautionary statements | P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312 |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22-36/37/38-R36/37/38-R20/21/22 |
| Safety Statements | 26-36-S36-S26-24/25 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
