Home Categories Chemical Reagents 1,10-Phenanthroline-5,6-Dione
A6677412

1,10-Phenanthroline-5,6-Dione , 97% , 27318-90-7

Synonym(s):
phd;Stahl phd oxidant

CAS NO.:27318-90-7

Empirical Formula: C12H6N2O2

Molecular Weight: 210.19

MDL number: MFCD00014473

Pack Size Price Stock Quantity
250MG RMB28.80 In Stock
1G RMB63.20 In Stock
5G RMB235.20 In Stock
25g RMB1013.60 In Stock
100g RMB2799.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 260 °C (dec.)(lit.)
Boiling point: 456.1±20.0 °C(Predicted)
Density  1.444±0.06 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
pka 0.26±0.20(Predicted)
form  powder to crystal
color  Light yellow to Amber to Dark green
Water Solubility  Insoluble in water.
λmax 251nm(MeOH)(lit.)
InChI InChI=1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H
InChIKey KCALAFIVPCAXJI-UHFFFAOYSA-N
SMILES N1C2=C(C(=O)C(=O)C3=C2N=CC=C3)C=CC=1

Description and Uses

1,10-Phenanthroline-5,6-dione is a Bifunctional quinone oxidant which, when used in conjunction with Zn2+ catalysts, is used to affect the aerobic oxidation of secondary amines to a variety of value added motifs, including indoles.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29349990

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