[2.2]Paracyclophan , 99% , 1633-22-3

Synonym(s):
Tricyclo[8.2.2.2^4,7]hexadeca-4,6,10,12,13,15-hexaene

CAS NO.：1633-22-3

Empirical Formula: C16H16

Molecular Weight: 208.3

MDL number: MFCD00003707

EINECS: 216-644-2

PRODUCT Properties

• Melting point: 285-288 °C(lit.)
• Boiling point: 282.51°C (rough estimate)
• Density: 1.0102 (estimate)
• vapor pressure: 0.001Pa at 25℃
• refractive index: 1.5000 (estimate)
• storage temp.: Sealed in dry,Room Temperature
• form: powder to crystal
• color: White to Almost white
• Water Solubility: INSOLUBLE
• BRN: 1910888
• InChI: InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2
• InChIKey: OOLUVSIJOMLOCB-UHFFFAOYSA-N
• SMILES: C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2
• LogP: 5.14 at 20℃
• NIST Chemistry Reference: [2.2]Paracyclophane(1633-22-3)
• EPA Substance Registry System: Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3)

Description and Uses

[2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction^[1].

2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit.

Safety

• Symbol(GHS): GHS07
• Signal word: Warning
• Hazard statements: H302-H315-H319-H332-H335
• Precautionary statements: P261-P280-P305+P351+P338
• Hazard Codes: Xi,C,F
• Risk Statements: 11-34
• Safety Statements: 24/25-45-36/37/39-26-16
• WGK Germany: 3
• RTECS: YD2404000
• Hazard Note: Irritant
• TSCA: Yes
• HS Code: 29029080