A6638912
Phenylmagnesium Bromide , 1.0MinTHF , 100-58-3
Synonym(s):
PhMgBr solution
CAS NO.：100-58-3
Empirical Formula: C6H5BrMg
Molecular Weight: 181.31
MDL number: MFCD00000038
EINECS: 202-867-2
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 153-154 °C |
| Density | 1.134 g/mL at 25 °C |
| Flash point: | −40 °F |
| storage temp. | water-free area |
| solubility | Miscible with tetrahydrofuran. |
| form | Liquid |
| color | Yellow to brown |
| Specific Gravity | 1.14 |
| Water Solubility | reacts |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3588849 |
| InChIKey | ANRQGKOBLBYXFM-UHFFFAOYSA-M |
Description and Uses
Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Safety
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H225-H302-H314 |
| Precautionary statements | P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338 |
| Hazard Codes | F+,C,F |
| Risk Statements | 12-14-22-34-19-11-67-40-37 |
| Safety Statements | 16-26-36/37/39-45-33-29-7/8-6A-43B |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| F | 1-3-10 |
| TSCA | Yes |
| HazardClass | 4.3 |
| PackingGroup | II |
| HS Code | 29319090 |
