PRODUCT Properties
Melting point: | -29 °C (lit.) |
Boiling point: | 135 °C/761 mmHg (lit.) |
Density | 1.03 g/mL at 25 °C (lit.) |
FEMA | 3309 | 2-METHYLPYRAZINE |
refractive index | n |
Flash point: | 122 °F |
storage temp. | 2-8°C |
solubility | >20.87 mg/mL in EtOH with ultrasonic; >49.9 mg/mL in DMSO; |
form | Liquid |
pka | 1.45(at 27℃) |
color | Clear colorless to slightly yellow |
Odor | at 1.00 % in dipropylene glycol. nutty cocoa roasted chocolate peanut green |
Odor Type | nutty |
Water Solubility | Fully miscible in water. |
JECFA Number | 761 |
BRN | 105778 |
InChIKey | CAWHJQAVHZEVTJ-UHFFFAOYSA-N |
LogP | 0.18 |
Description and Uses
2-Methylpyrazine has an odor threshold in water variously reported at 60,000 or 105,000 ppb. May be prepared from the corresponding carboxylic acid; by catalytic dehydrogenation of 2-methyl-piperazine; by condensation of methylglyoxal with ethylenediamine.
2-Methylpyrazine is used as flavoring agents in bread fresh bread, butter, chocolate, chocolate cocoa, coffee, meat roasted, nut almond.
Safety
Symbol(GHS) | GHS02,GHS07 |
Signal word | Warning |
Hazard statements | H226-H302 |
Precautionary statements | P210-P233-P240-P241-P242-P301+P312 |
Hazard Codes | Xn,Xi,F |
Risk Statements | 10-22-36/37/38 |
Safety Statements | 26-36-16 |
RIDADR | UN 1993 3/PG 3 |
WGK Germany | 3 |
RTECS | UQ3675000 |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | III |
HS Code | 29339990 |
Toxicity | mouse,LD50,intraperitoneal,1820mg/kg (1820mg/kg),Toxicology and Applied Pharmacology. Vol. 17, Pg. 244, 1970. |