A5579112
Malonitrile , 1000μg/ml,inPurgeandTrapMethanol , 109-77-3
Synonym(s):
Dicyanomethane;Malonodinitrile;Malononitrile
CAS NO.：109-77-3
Empirical Formula: C3H2N2
Molecular Weight: 66.06
MDL number: MFCD00001883
EINECS: 203-703-2
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 30-32 °C (lit.) |
| Boiling point: | 220 °C (lit.) |
| Density | 1.049 g/mL at 25 °C (lit.) |
| vapor pressure | 1 hPa (50 °C) |
| refractive index | 1.4150 |
| Flash point: | 234 °F |
| storage temp. | 2-8°C |
| solubility | 133g/l |
| pka | 11(at 25℃) |
| form | Crystalline Low Melting Mass |
| color | White to yellow-brown |
| Specific Gravity | 1.049 |
| PH | pH : 4.5 |
| Water Solubility | 13.3 g/100 mL (20 ºC) |
| Merck | 14,5711 |
| BRN | 773697 |
| Exposure limits | TLV-TWA 8 mg/m3 (3 ppm) (NIOSH). |
| Dielectric constant | 46.0 |
| InChIKey | CUONGYYJJVDODC-UHFFFAOYSA-N |
| CAS DataBase Reference | 109-77-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Malononitrile(109-77-3) |
| EPA Substance Registry System | Malononitrile (109-77-3) |
Description and Uses
Malonitrile, also known as Malononitrile, is an aliphatic nitrile that can release cyanide through chemical or biological transformation. It was also used decades ago for treating certain forms of mental illness.
Malononitrile is an important building block for the syntheses of pharmaceuticals (e.g. triamterene, adenine and methotrexate), thiamin (vitamin B1), pesticides dyestuffs for color photography and synthetic fibers (e.g. vinylidene cyanide). Product Data Sheet
Safety
| Symbol(GHS) |   GHS06,GHS09 |
| Signal word | Danger |
| Hazard statements | H300-H311+H331-H317-H319-H410 |
| Precautionary statements | P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338 |
| Hazard Codes | T,N |
| Risk Statements | 23/24/25-50/53 |
| Safety Statements | 23-27-45-60-61 |
| RIDADR | UN 2647 6.1/PG 2 |
| OEB | B |
| OEL | TWA: 3 ppm (8 mg/m3) |
| WGK Germany | 3 |
| RTECS | OO3150000 |
| F | 8 |
| Autoignition Temperature | 365 °C |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | II |
| HS Code | 29269090 |
| Hazardous Substances Data | 109-77-3(Hazardous Substances Data) |
| Toxicity | LD50 i.p. in mice: 12.9 mg/kg (Jones, Israel) |
