2-Methoxyethyl ether , >99.0%(GC) , 111-96-6
Synonym(s):
‘Diglyme’;2-Methoxyethyl ether;Bis(2-methoxyethyl) ether;diEGdiME;Dimethyldiglycol
CAS NO.：111-96-6
Empirical Formula: C6H14O3
Molecular Weight: 134.17
MDL number: MFCD00008503
EINECS: 203-924-4
| Pack Size | Price | Stock | Quantity |
| 500ML | RMB44.00 | In Stock |
|
| 5L | RMB320.80 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | -64 °C (lit.) |
| Boiling point: | 162 °C (lit.) |
| Density | 0.944 g/mL at 20 °C (lit.)
0.939 g/mL at 25 °C (lit.) |
| vapor density | 4.6 (vs air) |
| vapor pressure | 3 mm Hg ( 20 °C) |
| refractive index | n |
| Flash point: | 134.6 °F |
| storage temp. | Store below +30°C. |
| solubility | Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly) |
| form | Liquid |
| color | ≤10(APHA) |
| Relative polarity | 0.244 |
| Odor | Mild ethereal. |
| explosive limit | 1.4-17.4%(V) |
| Water Solubility | Miscible |
| Sensitive | Hygroscopic |
| λmax | λ: 225 nm Amax: 1.00 λ: 240 nm Amax: 0.50 λ: 260 nm Amax: 0.20 λ: 280 nm Amax: 0.08 λ: 320-400 nm Amax: 0.01 |
| Merck | 14,3165 |
| BRN | 1736101 |
| Dielectric constant | 7.2999999999999998 |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. May be air or light sensitive. |
| InChIKey | SBZXBUIDTXKZTM-UHFFFAOYSA-N |
| LogP | -0.36 at 25℃ |
| CAS DataBase Reference | 111-96-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Ethane, 1,1'-oxybis[2-methoxy-(111-96-6) |
| EPA Substance Registry System | Diethylene glycol dimethyl ether (111-96-6) |
Description and Uses
Bis (2-methoxyethyl) ether, also known as diglyme, is a linear aliphatic diether widely used as a solvent and present as a clear liquid at room temperature with a mild ether odor. The compound is notknown to occur in nature. It is synthesized from ethylene oxide and methanol in the presence of either acidic or basic catalysts. The reaction is based on the classic Williamson ether synthesis. It can also be produced from diethylene glycol and dimethyl sulfate. In June 2012, ECHA proposed addition of diglyme to the REACH very high concern list.
Bis (2-methoxyethyl) ether, due to being chemically inert and possessing excellent solvent properties, is mainly used as a solvent and an anhydrous reaction medium for organometallic synthesis. It is also used as a solubilizer.
Safety
| Symbol(GHS) |   GHS02,GHS08 |
| Signal word | Danger |
| Hazard statements | H226-H360FD |
| Precautionary statements | P202-P210-P233-P240-P241-P308+P313 |
| Hazard Codes | T |
| Risk Statements | 60-61-10-19 |
| Safety Statements | 53-45 |
| RIDADR | UN 3271 3/PG 3 |
| WGK Germany | 1 |
| RTECS | KN3339000 |
| F | 3-10-23 |
| Autoignition Temperature | 370 °F |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29091990 |
| Hazardous Substances Data | 111-96-6(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 4760 mg/kg |
