A5261812
Lithium tri-sec-butylborohydride solution , 1MinTHF , 38721-52-7
Synonym(s):
Lithium tri-sec-butylborohydride solution
CAS NO.:38721-52-7
Empirical Formula: C12H25BLi
Molecular Weight: 187.08
MDL number: MFCD00011708
EINECS: 254-101-1
Pack Size | Price | Stock | Quantity |
25ML | RMB207.20 | In Stock |
|
100ML | RMB635.20 | In Stock |
|
500ml | RMB2511.20 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Density | 0.89 g/mL at 25 °C |
Flash point: | 1 °F |
storage temp. | Flammables area |
solubility | Miscible with tetrahydrofuran. |
form | Liquid |
color | Colorless to yellow |
Water Solubility | reacts |
Sensitive | Moisture Sensitive |
BRN | 4007327 |
InChIKey | ACJKNTZKEFMEAK-UHFFFAOYSA-N |
Description and Uses
Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions.
Safety
Symbol(GHS) | GHS02,GHS05,GHS07,GHS08 |
Signal word | Danger |
Hazard statements | H318-H225-H250-H260-H314-H335-H351 |
Precautionary statements | P310-P370+P378i-P402+P404-P210-P231+P232-P280-P305+P351+P338-P370+P378-P422 |
Hazard Codes | F,C |
Risk Statements | 11-14/15-17-34-35-19-40-37 |
Safety Statements | 16-26-36/37/39-43-45-7/8-30 |
RIDADR | UN 3394 4.2/PG 1 |
WGK Germany | 1 |
F | 10 |
TSCA | Yes |
HazardClass | 4.3 |
PackingGroup | II |
HS Code | 29319090 |