Home Categories Organic Chemistry Lithium tri-sec-butylborohydride solution
A5261812

Lithium tri-sec-butylborohydride solution , 1MinTHF , 38721-52-7

Synonym(s):
Lithium tri-sec-butylborohydride solution

CAS NO.:38721-52-7

Empirical Formula: C12H25BLi

Molecular Weight: 187.08

MDL number: MFCD00011708

EINECS: 254-101-1

Pack Size Price Stock Quantity
25ML RMB207.20 In Stock
100ML RMB635.20 In Stock
500ml RMB2511.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Density  0.89 g/mL at 25 °C
Flash point: 1 °F
storage temp.  Flammables area
solubility  Miscible with tetrahydrofuran.
form  Liquid
color  Colorless to yellow
Water Solubility  reacts
Sensitive  Moisture Sensitive
BRN  4007327
InChIKey ACJKNTZKEFMEAK-UHFFFAOYSA-N

Description and Uses

Lithium triisobutylhydroborate is used as a reducing agent. Reagent for: Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters. Diastereoselective reduction reactions. Hydride reduction of the Danishefsky pyranones. Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes. Synthesis of alkanols by carbonylation reactions.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H318-H225-H250-H260-H314-H335-H351
Precautionary statements  P310-P370+P378i-P402+P404-P210-P231+P232-P280-P305+P351+P338-P370+P378-P422
Hazard Codes  F,C
Risk Statements  11-14/15-17-34-35-19-40-37
Safety Statements  16-26-36/37/39-43-45-7/8-30
RIDADR  UN 3394 4.2/PG 1
WGK Germany  1
10
TSCA  Yes
HazardClass  4.3
PackingGroup  II
HS Code  29319090

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