A4290312
4-Formylphenylboronic acid , 97% , 87199-17-5
Synonym(s):
p-Formylbenzeneboronic acid;p-Formylphenylboronic acid;4-(Dihydroxyboryl)benzaldehyde;4-Boronobenzaldehyde;4-Formylbenzeneboronic acid
CAS NO.:87199-17-5
Empirical Formula: C7H7BO3
Molecular Weight: 149.94
MDL number: MFCD00151823
EINECS: 438-670-5
Pack Size | Price | Stock | Quantity |
1G | RMB24.00 | In Stock |
|
5G | RMB52.00 | In Stock |
|
25G | RMB156.00 | In Stock |
|
100G | RMB495.20 | In Stock |
|
500g | RMB2102.40 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 237-242 °C (lit.) |
Boiling point: | 347.6±44.0 °C(Predicted) |
Density | 1.24±0.1 g/cm3(Predicted) |
vapor pressure | 0Pa at 25℃ |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
solubility | <10g/l |
form | Liquid |
pka | 7.34±0.10(Predicted) |
color | Clear colorless to yellow-orange |
PH | 5.5 (1g/l, H2O, 20℃) |
Water Solubility | Slightly Soluble in water. |
Sensitive | Air Sensitive |
BRN | 3030770 |
InChIKey | VXWBQOJISHAKKM-UHFFFAOYSA-N |
LogP | 1.36 at 20℃ |
Description and Uses
4-Formylphenylboronic acid is a substrate for Suzuki cross-coupling reactions and it can be used as a reagent for:
- Palladium-catalyzed Suzuki-Miyaura cross-coupling in water.
- Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides.
- Ligand-free copper-catalyzed coupling of nitro arenes with arylboronic acids.
- Triethylamine-catalyzed three-component Hantzsch condensations.
- Copper-catalyzed nitrations.
- Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta.
- Palladacycle-catalyzed cross-coupling of arylboronic acids with carboxylic anhydrides or acyl chlorides.
- Palladium-catalyzed aerobic oxidative cross-coupling reactions.
- The synthesis of sensitizers with dithiafulvenyl unit as electron donor for high-efficiency dye-sensitized solar cells.
- The synthesis of a novel protein synthesis inhibitor active against Gram-positive bacteria.
- The Suzuki aryl-aryl coupling of the upper rim of hexahomotrioxacalix[3]arene.
- A rhodium-catalyzed cyclization, converting 1,5-enynes to cyclopentenes and spiro-cyclopentenes.
Safety
Symbol(GHS) | GHS07 |
Signal word | Warning |
Hazard statements | H317 |
Precautionary statements | P261-P272-P280-P302+P352-P333+P313-P362+P364 |
Hazard Codes | C,Xi |
Risk Statements | 34-36/37/38 |
Safety Statements | 22-26-36/37/39-45-37/39-36 |
RIDADR | UN 1759 8/PG 3 |
WGK Germany | 3 |
F | 10 |
Hazard Note | Irritant |
TSCA | T |
HazardClass | IRRITANT, AIR SENSITIVE |
HS Code | 29163990 |