Home Categories Chemical Reagents Ethyl 2-Chloro-2-(hydroxyimino)acetate
A4083812

Ethyl 2-Chloro-2-(hydroxyimino)acetate , ≥98.0%(T) , 14337-43-0

Synonym(s):
1-Ethyl oxalyl chloride 2-oxime

CAS NO.:14337-43-0

Empirical Formula: C4H6ClNO3

Molecular Weight: 151.55

MDL number: MFCD00010209

EINECS: 604-347-4

Pack Size Price Stock Quantity
1g RMB24.00 In Stock
5G RMB60.80 In Stock
25G RMB179.20 In Stock
100G RMB610.40 In Stock
others     Enquire
Update time: 2022-07-08

PRODUCT Properties

Melting point: 70-76 °C (lit.)
Boiling point: 230.5±23.0 °C(Predicted)
Density  1.36±0.1 g/cm3(Predicted)
storage temp.  2-8°C
solubility  soluble in Methanol
form  powder to crystal
pka 7.60±0.10(Predicted)
color  White to Almost white
Sensitive  Moisture Sensitive/Lachrymatory
BRN  606193

Description and Uses

Ethyl 2-chloro-2-(hydroxyimino)acetate has been used:

  • in the preparation of (+)-and (?)-Δ2-isoxazolines
  • in the synthesis of CIP-AS (?), a chiral amino acid structurally related to glutamic acid, potential agonist at the ionotropic (±±)-2-amino-3-(3-hydroxy-5-methylisoxazol-4-yl)propionic acid (AMPA)-kainate receptors
  • to generate ethoxycarbonylformonitrile oxide, in situ by treatment with sodium bicarbonate
  • to prepare N-azirdinyloximes which on treatment with scandium triflate (418218) provide dihydro-oxadiazines

Safety

Symbol(GHS) 
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H318-H334-H335
Precautionary statements  P261-P280-P305+P351+P338-P342+P311
Hazard Codes  Xn,Xi
Risk Statements  37/38-41-42/43-36/37/38
Safety Statements  22-26-36/37/39-45-36
RIDADR  UN 3335
WGK Germany  3
10-19-21
HS Code  29280000

RELATED PRODUCTS