Home Categories Chemical Reagents DIBUTYLBORON TRIFLUOROMETHANESULFONATE
A3824712

DIBUTYLBORON TRIFLUOROMETHANESULFONATE , 0.7mol/Lindiethylether,Energyseal , 60669-69-4

Synonym(s):
Dibutylboron triflate solution

CAS NO.:60669-69-4

Empirical Formula: C9H18BF3O3S

Molecular Weight: 274.11

MDL number: MFCD00009669

Pack Size Price Stock Quantity
25ML RMB575.20 In Stock
100ML RMB1575.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 37℃ (0.12 Torr)
Density  1.271 g/mL at 25 °C
Flash point: 80 °F
storage temp.  2-8°C
form  Solution
color  Clear light yellow to orange
BRN  1968660
InChIKey FAVAVMFXAKZTMV-UHFFFAOYSA-N

Description and Uses

Dibutylboryl trifluoromethanesulfonate may be used in the following studies:

  • Stereo- and regio-selective synthesis of erythro aldols.
  • As a promoter for the solution and polymer-supported trichloroacetimidate-based glycosylations.
  • Synthesis of β-alkoxy carbonyl compounds via one-step Mukaiyama aldol-type reaction.
  • Aldol-type cyclization for the stereoselective synthesis of cyclic ethers.
  • As a reagent for the formation of boron enolates.
  • As a complexation aid for the isolation of 1-acyldipyrromethanes.
  • As a promoter in [1,2]-Wittig reaction between aldehydes and O-benzyl or O-allyl glycolate esters, creating two contiguous stereocenters (1,2-diol) in good yield without the need for strong base.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H226-H314-H335-H336-H351-H373
Precautionary statements  P261-P280-P305+P351+P338-P310
Hazard Codes  C,F+,F
Risk Statements  12-22-34-66-67-40-10-37-65-48/20-11-63-19
Safety Statements  9-16-26-33-36/37/39-45-62
RIDADR  UN 2924 3/PG 1
WGK Germany  3
1-10
HazardClass  3.2
PackingGroup  III
HS Code  29310099

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