A3201912
Diethyl oxalate , AR,99% , 95-92-1
Synonym(s):
Diethyl oxalate;Oxalic acid diethyl ester
CAS NO.：95-92-1
Empirical Formula: C6H10O4
Molecular Weight: 146.14
MDL number: MFCD00009119
EINECS: 202-464-1
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -41 °C (lit.) |
| Boiling point: | 185 °C (lit.) |
| Density | 1.076 g/mL at 25 °C (lit.) |
| vapor density | 5.03 (vs air) |
| vapor pressure | 1 mm Hg ( 47 °C) |
| refractive index | n |
| Flash point: | 168 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with alcohols, ether and other common organic solvents. |
| form | Liquid |
| color | Clear |
| explosive limit | 0.42-2.67%(V) |
| Water Solubility | MAY DECOMPOSE |
| Sensitive | Moisture Sensitive |
| Merck | 14,3125 |
| BRN | 606350 |
| Dielectric constant | 8.2（21℃） |
| Stability: | Stable, but moisture sensitive. Incompatible with strong oxidizing agents. |
| InChIKey | WYACBZDAHNBPPB-UHFFFAOYSA-N |
| LogP | 0.560 |
| CAS DataBase Reference | 95-92-1(CAS DataBase Reference) |
| NIST Chemistry Reference | Ethanedioic acid, diethyl ester(95-92-1) |
| EPA Substance Registry System | Ethyl oxalate (95-92-1) |
Description and Uses
Diethyl oxalate is used to prepare active pharmaceutical ingredients (API), plastics and dyestuff intermediates. It is also used as a solvent for cellulose esters, ethers, resins, perfumes and lacquers for electronics. It is involved in the transesterification reaction with phenol to get dipheny oxalate. It is also involved in the Claisen condensation ketosteroids to prepare glyoxalyl derivatives. Further, it is used to prepare sym-1,4-diphenyl-1,4-dihydro-1,2,4,5-polytetrazine. In addition to this, it is utilized in the microemulsion synthesis of zinc oxide nanoparticles.
Safety
| Symbol(GHS) |    GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H302-H314-H373 |
| Precautionary statements | P260-P280-P301+P312-P303+P361+P353-P305+P351+P338-P314 |
| Hazard Codes | Xn,T |
| Risk Statements | 22-36-68/21-48/25-35-61-60 |
| Safety Statements | 23-45-36/37/39-28-26-25-24-53 |
| RIDADR | UN 2525 6.1/PG 3 |
| WGK Germany | 1 |
| RTECS | RO2800000 |
| Autoignition Temperature | 410 °C |
| TSCA | Yes |
| HazardClass | 6.1 |
| PackingGroup | III |
| HS Code | 29171900 |
| Hazardous Substances Data | 95-92-1(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 400 mg/kg |
