A3198512
Dess-Martin Periodinane , 96% , 87413-09-0
Synonym(s):
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
CAS NO.:87413-09-0
Empirical Formula: C13H13IO8
Molecular Weight: 424.14
MDL number: MFCD00130127
EINECS: 672-328-8
Pack Size | Price | Stock | Quantity |
1G | RMB23.20 | In Stock |
|
5G | RMB40.80 | In Stock |
|
25G | RMB95.20 | In Stock |
|
100g | RMB355.20 | In Stock |
|
250g | RMB783.20 | In Stock |
|
500g | RMB1420.00 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 130-133 °C (lit.) |
Boiling point: | 40 °C |
Density | 1.369 g/mL at 25 °C |
Flash point: | >221 °F |
storage temp. | -20°C |
solubility | Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane. |
form | Liquid |
color | Colorless to light yellow |
Sensitive | Light Sensitive |
Merck | 14,2933 |
BRN | 4548207 |
Stability: | Light Sensitive |
InChI | InChI=1S/C13H13IO8/c1-8(15)19-14(20-9(2)16,21-10(3)17)12-7-5-4-6-11(12)13(18)22-14/h4-7H,1-3H3 |
InChIKey | NKLCNNUWBJBICK-UHFFFAOYSA-N |
SMILES | I1(OC(=O)C)(OC(=O)C)(OC(=O)C)OC(=O)C2C=CC=CC1=2 |
CAS DataBase Reference | 87413-09-0(CAS DataBase Reference) |
Description and Uses
Dess-Martin periodinane (DMP) is a hypervalent iodine compound widely used as a mild reagent for the oxidation of primary/secondary alcohols to aldehydes/ketones; oxidation of amides into imides; the dehydrogenation of amines to nitriles, and disulfides to sulfones. It is also used to selectively oxidize alkenes to epoxides. This is a useful reaction for generating three-membered cyclic ethers. Additionally, DMP is used to oxidatively cleave 1,2-diols to form aldehydes or ketones and in the synthesis of lactones.
Oxidizing reagent.
Safety
Symbol(GHS) | GHS03,GHS07 |
Signal word | Danger |
Hazard statements | H272-H315-H319-H335 |
Precautionary statements | P210-P220-P261-P264-P302+P352-P305+P351+P338 |
Hazard Codes | Xn,O,Xi |
Risk Statements | 22-36/37/38-40-8-20/21/22-44 |
Safety Statements | 26-36-36/37-24/25-23-17-45-36/37/39 |
RIDADR | UN 1593 6.1/PG 3 |
WGK Germany | 3 |
Hazard Note | Harmful/Light sensitive |
TSCA | No |
HazardClass | 5.1 |
PackingGroup | Ⅲ |
HS Code | 29349990 |