A3191212
Diphenyl sulfoxide , 99% , 945-51-7
Synonym(s):
Phenyl sulfoxide
CAS NO.:945-51-7
Empirical Formula: C12H10OS
Molecular Weight: 202.27
MDL number: MFCD00002085
EINECS: 213-415-9
Pack Size | Price | Stock | Quantity |
5G | RMB24.00 | In Stock |
|
25G | RMB35.20 | In Stock |
|
100G | RMB102.40 | In Stock |
|
500G | RMB439.20 | In Stock |
|
2.5kg | RMB2079.20 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 69-71 °C (lit.) |
Boiling point: | 206-208 °C/13 mmHg (lit.) |
Density | 1.1833 (rough estimate) |
refractive index | 1.6090 (estimate) |
Flash point: | 206-208°C/13mm |
storage temp. | Sealed in dry,Room Temperature |
solubility | Chloroform (Slightly), DMSO (Slightly) |
form | Crystalline Powder |
color | White to off-white |
Water Solubility | Soluble in water. Soluble in most organic solvents. |
BRN | 1908444 |
InChIKey | JJHHIJFTHRNPIK-UHFFFAOYSA-N |
Description and Uses
Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.
Safety
Symbol(GHS) | GHS02 |
Signal word | Danger |
Hazard statements | H225 |
Precautionary statements | P210-P403+P235 |
Hazard Codes | Xi |
Safety Statements | 22-24/25 |
WGK Germany | 3 |
RTECS | DA9185000 |
Hazard Note | Irritant |
TSCA | Yes |
HS Code | 29309070 |