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A3181712

Diisopropylamine , Analysis of standard products,> 99.5%(GC) , 108-18-9

Synonym(s):
Diisopropyl amine;Diisopropylamine;DIPA

CAS NO.:108-18-9

Empirical Formula: C6H15N

Molecular Weight: 101.19

MDL number: MFCD00008862

EINECS: 203-558-5

Update time: 2022-07-08

PRODUCT Properties

Melting point: -61 °C (lit.)
Boiling point: 84 °C (lit.)
Density  0.722 g/mL at 25 °C (lit.)
vapor density  3.5 (vs air)
vapor pressure  50 mm Hg ( 20 °C)
refractive index  n20/D 1.392(lit.)
Flash point: 1.4 °F
storage temp.  Store below +30°C.
solubility  100 g/L (20°C)
pka 11.05(at 25℃)
form  Liquid
color  Clear colorless
PH 11.8 (6g/l, H2O, 20℃)
Odor Amine.
explosive limit 1.1-7.1%(V)
Water Solubility  100 g/L (20 ºC)
Merck  14,3196
BRN  605284
Exposure limits NIOSH REL: TWA 5 ppm (20 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 5 ppm; ACGIH TLV: TWA 5 ppm (adopted).
Dielectric constant 3.04
Stability: Stable. Flammable. Incompatible with strong oxidizing agents. May react violently with strong acids or oxidizers. Air sensitive.
InChIKey UAOMVDZJSHZZME-UHFFFAOYSA-N
LogP 0.4 at 20℃

Description and Uses

Diisopropylamine is a secondary amine and is a colorless liquid at room temperature with a fishy, ammonia-like odor. It is used as a chemical intermediate, and catalyst for the synthesis of pesticides and pharmaceuticals. Diisopropylamine is associated with tobacco either as a natural component of tobacco, pyrolysis product (in tobacco smoke), or additive for one or more types of tobacco products. Synonyms for diisopropylamine include DIPA, and N-(1-methylethyl)-2- propanamine.

Diisopropylamine is used as a precursor to prepare lithium diisopropylamide and sulfenamides, which are used in rubber vulcanization. It is also involved in the synthesis of N,N-Diisopropylethylamine (Hünig's base) obtained by alkylation with diethyl sulfate. Diisopropylammonium bromide is a bromide salt of DIPA used as an inert alternative to barium titanate. It is widely used as solvent as well as an intermediate in the the synthesis of pharmaceuticals, dyes, mineral flotation agents and emulsifiers.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H225-H302-H314-H331-H335-H412
Precautionary statements  P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,C
Risk Statements  11-20/22-34
Safety Statements  16-26-36/37/39-45
OEB A
OEL TWA: 5 ppm (20 mg/m3) [skin]
RIDADR  UN 1158 3/PG 2
WGK Germany  2
RTECS  IM4025000
Autoignition Temperature 599 °F
Hazard Note  Highly Flammable/Corrosive/Harmful
TSCA  Yes
HS Code  2921 19 99
HazardClass  3
PackingGroup  II
Toxicity LD50 orally in rats: 0.77 g/kg (Smyth)
IDLA 200 ppm

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