Diisobutylaluminum hydride , 1.0Minhexanes , 1191-15-7
Synonym(s):
DIBAL;DIBAL-H
CAS NO.：1191-15-7
Empirical Formula: C8H19Al
Molecular Weight: 142.22
MDL number: MFCD00008928
EINECS: 214-729-9
| Pack Size | Price | Stock | Quantity |
| 25ML | RMB126.40 | In Stock |
|
| 100ML | RMB172.80 | In Stock |
|
| 500ML | RMB380.00 | In Stock |
|
| 1L | RMB716.00 | In Stock |
|
| others | Enquire |
PRODUCT Properties
| Melting point: | -70 °C |
| Boiling point: | 65 °C |
| Density | 1.23 g/mL at 25 °C |
| vapor pressure | 13.3Pa at 90℃ |
| Flash point: | 40 °F |
| storage temp. | 2-8°C |
| solubility | Miscible with organic solvents. |
| form | Solution |
| Specific Gravity | 0.860 |
| color | Clear |
| Water Solubility | vigorous reaction |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Air Sensitive/Heat Sensitive |
| BRN | 4123663 |
| Exposure limits | ACGIH: TWA 20 ppm OSHA: Ceiling 300 ppm; TWA 200 ppm NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3) |
| InChIKey | AZWXAPCAJCYGIA-UHFFFAOYSA-N |
| LogP | 4.22 |
| CAS DataBase Reference | 1191-15-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Diisobutylaluminum hydride(1191-15-7) |
| EPA Substance Registry System | Diisobutylaluminum hydride (1191-15-7) |
Description and Uses
Diisobutylaluminium hydride (DIBALH, DIBAL, DIBAL-H or DIBAH) is a reducing agent with the formula (i-Bu2AlH)2, where i-Bu represents isobutyl (-CH2CH(CH3)2). It can be used for various homogeneous reductions such as alkynes to alkenes, esters or nitriles to aldehydes. It is available commercially as the neat reagent and as a solution in several different solvents (hexane, dichloromethane, tetrahydrofuran, etc.). The neat reagent is a liquid and is supplied in metal cylinders. It is pyrophoric and highly reactive and therefore must be handled with great care. The molar solutions in organic solvents are more stable and easier to handle provided that the normal precautions are taken for working with air-sensitive compounds. They must all be handled in an atmosphere free from oxygen and water. Commonly used solvents for diisobutylaluminium hydride are dichloromethane, diglyme, dioxane and tetrahydrofuran. Even when the substrate is not completely soluble in these solvents successful reductions can be accomplished.
Diisobutylaluminum hydride is used as reducing agent in pharmaceuticals. It is also used as raw material in organic synthesis, agrochemicals and dyestuffs.
Safety
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H250-H260-H304-H314-H336-H361d-H373-H412 |
| Precautionary statements | P210-P231+P232-P280-P301+P310+P331-P301+P330+P331-P303+P361+P353-P305+P351+P338+P310-P370+P378 |
| Hazard Codes | F,T,C,N |
| Risk Statements | 14/15-17-35-40-67-65-63-48/20-11-34-19-62-51/53-23/24/25-20/21/22-15-14-50/53-37-22 |
| Safety Statements | 26-43-45-62-46-36/37/39-29-16-61-27-9 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 2 |
| RTECS | BD0710000 |
| F | 1-4.3-10 |
| TSCA | Yes |
| HazardClass | 4.3 |
| PackingGroup | I |
| HS Code | 29319090 |
| Hazardous Substances Data | 1191-15-7(Hazardous Substances Data) |
