Home Categories Organic Chemistry Triisobutylaluminum
A2950157

Triisobutylaluminum , 1.0Mintoluene , 100-99-2

Synonym(s):
Aluminumtriisobutanide;TIBA;TIBA solution

CAS NO.:100-99-2

Empirical Formula: C12H27Al

Molecular Weight: 198.32

MDL number: MFCD00008929

EINECS: 202-906-3

Update time: 2022-07-08

PRODUCT Properties

Melting point: 4-6°C
Boiling point: 68-69 °C
Density  0.848 g/mL at 25 °C
vapor pressure  75Pa at 25℃
refractive index  1.4494
Flash point: −1 °F
storage temp.  0-6°C
form  Solution
Specific Gravity 0.848
color  Clear colorless to light yellow
Water Solubility  reacts
Hydrolytic Sensitivity 10: reacts extremely rapidly with moisture and oxygen - may be pyrophoric - sealed system required
Sensitive  Air & Moisture Sensitive
Merck  14,326
BRN  3587328
Exposure limits ACGIH: TWA 50 ppm (Skin)
OSHA: TWA 500 ppm(1800 mg/m3)
NIOSH: IDLH 1100 ppm; TWA 50 ppm(180 mg/m3)
InChIKey MCULRUJILOGHCJ-UHFFFAOYSA-N

Description and Uses

Triisobutylaluminum is used as a reducingagent. It is also used in combinationwith transition metal compounds as aZiegler-Natta catalyst in polymerization andhydrogenation reactions. A dilute solution ofthe compound is employed in commercialapplications.

Safety

Symbol(GHS) 
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H250-H260-H304-H314-H336-H361d-H373-H412
Precautionary statements  P210-P231+P232-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338-P370+P378
Hazard Codes  F,C,N
Risk Statements  14-17-23/24/25-34-67-65-63-48/20-11-62-51/53
Safety Statements  26-36/37/39-45-61-62-6A-46-43A-16-27-43
RIDADR  UN 3394 4.2/PG 1
WGK Germany  2
RTECS  BD2203500
10
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29319090

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